Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
It is known that other substances will answer just as well as lime
in this new roasting process. Such substances are manganese and iron
oxides. Not only these two substances, but in fact any substance which
answers the purpose of diminishing the local strong evolution of heat,
due to the reaction:
PbS + 3O = PbO + SO₂,
serves just as well as the lime. This fact is proved by exhaustive
experiments in which mixtures of lead sulphide on the one hand, and
quartz, crushed lead slags, iron slags, crushed iron ores, crushed
copper slags, etc., on the other hand, were used for blowing. All
these substances are such that any chemical action, analogous to the
splitting up of CaO₂, or the formation of plumbates as suggested
by Dr. Borchers, cannot be imagined. The time is not yet ripe, without
more experiments on the subject, to assert conclusively that there
is no acceleration of the process due to the formation of plumbates
through the agency of lime. But the facts thus far secured point out
that such reactions are, at least, not of much importance.
Theoretical considerations point out that it ought to be possible to
avoid the injurious local increase of temperature during the progress
of this new roasting process, without having to add any substance
whatever. To explain: The first reaction taking place in the roasting is
PbS + 3O = PbO + SO₂ + 99.8 cal.
Now the heat thus liberated may be successfully dispersed if there is,
in simultaneous progress, the endothermic reaction:
PbS + 3PbSO₄ = 4PbO + 4SO₂ - 187 cal.
Hence if there could be obtained a mixture of lead sulphide and of
lead sulphate in the proportions demanded by the above reaction, then
such a mixture ought to be blown successfully to lead oxide without
the addition of any other substance. Such a process has, in fact, been
carried out. The original galena is heated until the required amount of
lead sulphate has been formed. Then the mixture of lead sulphide and
of lead sulphate is transferred to a converter and blown successfully
without the addition of any other substance.
The adaptability of an ore to the process just mentioned depends on
the cost of the preliminary roast and the thoroughness with which it
must be done. As is known, when lead sulphide is heated with access of
air, it is very easy to form sintered incrustations of lead sulphate.
If these incrustations are not broken up, or if their formation is not
prevented by diligent rabbling, the further access of air to the mass
is prevented and the oxidation of the charge stops. If ores with such
incrustations are placed in the converter without being crushed, they
remain unaltered by the blowing. If the incrustations are too numerous
the converting becomes a failure.
Public-domain text, read in full here on John Shaqi.
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