Leather: From the Raw Material to the Finished Product — John Shaqi
Leather: From the Raw Material to the Finished ProductAdcock, K. J.
History
Leather: From the Raw Material to the Finished Product
Adcock, K. J.
Leather
Imperfect preservation is another serious form of damage to hides and
one that cannot be easily remedied in some of the hot climates. Hides
and skins may be simply dried, salted and dried, wet-salted, treated
with arsenic solution and dried, brined or pickled with acid and
salt; of these methods the last-named is the most effective, but is
not practicable, or, at least, has not yet been applied practically
to the cure of hides and calf skins. Salt is not available, or is too
costly in most tropical countries; hence, Chinese, Indian, Mexican,
Colombian, and Arabian hides and skins are generally exported in
a dry condition. Even when the hides are dried under the best
conditions in a cool and shady place, they are of less value than a
fresh or a wet-salted hide, owing to a certain loss of gelatinous
matter in softening them before they can be placed in the lime
liquors. But it not infrequently happens that hides are dried by
exposure to the hot sun, or perhaps in a strong current of air. In
either case, the hide is much reduced in value and may be irreparably
ruined. The effect of submitting hides to these conditions is that
the exterior surface becomes rapidly dry and, naturally, contracted,
so that the air or heat cannot reach the interior, which retains
moisture. This moist inner layer may be quite thin, but it contains
sufficient nutrient to develop putrefactive organisms, so that when
the hide is soaked in water it practically falls to pieces. The
effect of hot sun or heat of any kind is, of course, disastrous to
raw hides and skins, and there have been not a few claims on shipping
companies as the result of storing hides near the boilers of ships.
Salt is almost invariably used for curing both hides and calf
skins, but though it is a good preservative it has one or two minor
defects. It contains too much water, and is liable to contain traces
of iron which is inimical to both raw hides and leather in process
of manufacture. Common salt is also liable to cause stains which
cannot be removed in later processes, and which are even accentuated
in the tan liquors. One trade chemist attributes these stains to
the presence of calcium sulphate (Ca. SO_{4}) or gypsum in the
salt, which is converted into calcium phosphate by the action of
the phosphoric acid in the nuclei of the hide on the sulphate of
calcium. Another well-known technical chemist is certain that stains
are produced by the growth of bacteria, and to prove his assertion
prepared in gelatine several cultures from salt-stained skins.
Practical men generally attribute the stains to the presence of
blood on the hides or skins at the time of curing, and the majority
of the stains are probably due to this cause, although the presence
of calcium sulphate as an impurity of the salt would undoubtedly
contribute to this defect. Blood contains a percentage of iron, and,
with other extraneous matters, should be washed from the hides before
salting them.
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