Leather: From the Raw Material to the Finished ProductAdcock, K. J.
History
Leather: From the Raw Material to the Finished Product
Adcock, K. J.
Leather
There are several recipes for making one-bath liquors. A favourite
mixture consists of chrome alum and sodium carbonate (common soda).
Another method consists of reducing a solution of chromic acid with
glucose or grape-sugar. This liquor has a greater plumping effect
on the leather than the chrome alum liquor has. A third process of
making a one-bath liquor combines the use of bichromate of potash and
chrome alum, which, when dissolved, is converted into a basic chrome
salt by means of a reducing agent. The one-bath liquor can be easily
and safely applied to hides and skins, and is used in much the same
manner as a vegetable tan liquor, beginning with a weak solution and
gradually increasing the strength until the process is completed.
The two-bath method needs great care, as a slight difference in the
proportions of the ingredients used may alter the character of the
leather produced.
The formula now largely used is practically the same as that of the
original patentee, Augustus Schultz, an American chemist. The first
bath, the chromic acid solution, is made by treating bichromate
of potash or soda with hydrochloric, sulphuric, or formic acids.
Bichromate of potash and hydrochloric acid (commonly known as
muriatic acid, or spirits of salts) are commonly used, and in the
proportion of 5 per cent. and 2-1/2 per cent. of the weight of the
drained pelts (5 lb. of bichromate and 2-1/2 lb. of acid for 100 lb.
of pelts). The chemical reaction is represented by the following
equation--
K_{2}Cr_{2}O_{7} + 2HCl = 2KCl + 2CrO_{3} + H_{2}O
Bichromate of potash + Hydrochloric Acid
= Potassium chloride + chromic acid + water.
Public-domain text, read in full here on John Shaqi.
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