Leather: From the Raw Material to the Finished ProductAdcock, K. J.
History
Leather: From the Raw Material to the Finished Product
Adcock, K. J.
Leather
This process is most conveniently carried out in the paddle-vat
(Fig. 25), which, in this case, should be fitted with a wooden cover
to exclude light, since the colour of the chromic acid liquor is
affected by strong light. Some chrome tanners prefer to use the drum
tumbler (Fig. 13), but the pounding of the skins by this method is
apt to make the grain loose. Whichever method be adopted, the hides
or skins should be horsed up to drain for several hours before
transferring them to the second bath. It is important that they be
placed grain to grain and smoothed out, as creases and air bubbles
between the skins become fixed in the second liquor, and depreciate
the value of the finished leather. To avoid this danger, many tanners
pass the hides or skins through a striking-out machine under light
pressure. Another detail of importance is to cover the chromed skins
with canvas or matting to keep them from the light. Although the
skins are preserved by chromic acid, they are not made into leather,
for in this condition they would dry quite horny. Hence, it is
undesirable that the hides should be dried at this stage and sold
as leather, although such a proceeding has been attempted. Further,
chromic acid is an irritant poison which may cause an eruption on
the hands and arms of workers handling the hides in this solution,
unless they are protected by rubber gloves, or by coating the hands
with a mixture of vaseline and lanoline. The second bath consists of
chemicals which reduce the chromic acid to the oxide, which is quite
inert, so that there is no danger whatever of contracting a poisoned
foot as the result of wearing chrome leather. The chemicals largely
used for the second bath are hyposulphite of soda and hydrochloric
acid. Sodium sulphite may also be used without the addition of acid.
The skins change from an orange colour to a pale, bluish-grey tint,
but the process is not completed until a cross section shows that
the colour has changed right through the skin. A suitable proportion
is 10 per cent. "hypo" and 2-1/2 per cent. acid (28° Twaddell)
calculated on the weight of the drained pelts. Calf, goat, and sheep
skins are usually treated in the drum, but hides, especially if a
certain degree of firmness is required, are preferably run in the
paddle-vat. The reaction of the chemicals in the second bath are
somewhat complicated, but the principal point is the reduction of the
chromic acid (CrO_{3}) to chromic oxide (Cr_{2}O_{3}).
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