Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence — John Shaqi
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
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Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
A wooden,--or better, a gutta-percha--cylinder (Fig. 1), 5 cubic
centimetres in height and from 20 to 25 c. c. in diameter, is employed.
A piece of moistened parchment is securely attached to one of the
openings of the cylinder, which, upon drying, shrinks and completely
closes the aperture. If its continuity becomes impaired, the pores of
the membrane should be covered with the white of an egg which is
subsequently coagulated by the application of heat. The organs
previously cut into small pieces, or the materials found in the
alimentary canal, etc., after having been allowed to digest for 24 hours
in water at 32°[A]--or, in dilute acids, if the presence of an alkaloid
is suspected,--are then placed in the upper vessel, which is termed the
dialyser. The whole should form a layer not over 2 cubic centimetres in
height. The dialyser is next placed in the larger vessel filled with
distilled water. In about 24 hours three-quarters of the crystalloid
substances present will have passed into the lower vessel. The solution
is then evaporated over a water-bath, and submitted to analysis. The
portion remaining in the dialyser is decomposed by one of the methods
previously described, in order to effect the detection of any poisonous
substances possibly present. Instead of the above apparatus, the one
represented in Fig. 2 can be employed. The fluid under examination is
placed in a bell-shaped jar, open at the top and closed below with a
piece of parchment, which is then suspended in the centre of a larger
vessel containing water. In other respects the operation is performed in
the same manner as with the apparatus represented in Fig. 1.
[Illustration: Fig. 2.]
[A] The degrees of temperature given in the text refer to the
centigrade Thermometer; their equivalents on the Fahrenheit scale can
be obtained by means of the formula:
9/5 C° + 32 = F°.
--_Trans._
II.
DETECTION OF POISONS, THE PRESENCE OF WHICH IS SUSPECTED.
DETECTION OF ARSENIC.
It is frequently required, in chemical jurisprudence, to institute a
search for arsenic in the remains of a deceased person, whose death is
supposed to have been caused by the reception of a poison. Under these
circumstances the poison is mixed with a mass of substances which would
obscure its characteristic properties, and it becomes necessary, in
order to accomplish its identification, to isolate it, and then, by
decisive reactions, determine its character. Three methods exist which
permit of this result; they are:
1st. The method used prior to Marsh's test.
2nd. Marsh's test.
3rd. A method more recent than Marsh's, proposed by _M. Raspail_.
METHOD USED PRIOR TO MARSH'S TEST.
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