Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
_b._ If the ring is dissolved in pure water and an ammoniacal solution
of sulphate of copper added, a beautiful green precipitate ("_Scheele's
green_"), consisting of arsenite of copper, is produced.
4. When produced by arsenic the spots are soluble in nitric acid, and
upon evaporating the solution so obtained to dryness, a residue of
arsenic acid, which is easily soluble in water, remains. If an
ammoniacal solution of nitrate of silver is added to the aqueous
solution of the residue, a brick-red precipitate is produced. Spots
consisting of antimony give, when treated with nitric acid, a residue of
an intermediate oxide, insoluble in water.
5. Upon treating the spots with a drop of solution of sulphide of
ammonium, the sulphide of the metal present is formed: if sulphide of
arsenic is produced its properties, as enumerated above, can be
recognized. It may be added that the sulphide of antimony formed is
soluble in hydrochloric acid, and possesses an orange red color, whereas
sulphide of arsenic is yellow.
6. When spots originating from arsenic are treated with a solution of
hypochlorite of soda (prepared by passing chlorine into solution of
carbonate of soda), they are immediately dissolved; if, on the other
hand, they are produced by antimony, they remain unaltered by this
treatment.
Such are the properties exhibited by soluble compounds of arsenic when
treated by Marsh's process; the following precautions are, however,
necessary when this test is made use of in medico-legal examinations.
1. If small white gritty particles, resembling arsenious acid, are
discovered in the stomach or intestines, they are directly introduced
into Marsh's apparatus. When this is not the case, the destruction of
the organic matter is indispensable even though, instead of the organs
themselves, the contents of the alimentary canal are taken. In the
latter instance, the solids are separated from the fluids present by
filtration, the solution evaporated to dryness and the residue united
with the solid portion; the organic matter is then destroyed by one of
the methods previously described. In the special case of arsenic, the
separation of the poison from the accompanying organic materials can be
accomplished by a process not yet mentioned which may prove to be of
service. The suspected substances are distilled with common salt and
concentrated sulphuric acid. By this operation the arsenic is converted
into a volatile chloride which distils over. The poison is isolated by
treating this compound with water, by which it is decomposed into
hydrochloric and arsenious acids. We must give preference, however, to
the method by means of chlorate of potassa and hydrochloric acid.
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