Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
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Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
Whether a residue remains or not, an excess of ammonia is next added to
the filtered solution in nitric acid: the formation of a permanent
precipitate denotes the presence of _bismuth_. In this case, the fluid
is filtered, and the alkaline filtrate further tested for copper and
cadmium. For this purpose, cyanide of potassium is added, and
sulphuretted hydrogen conducted through the filtrate: if _cadmium_ be
present, a yellow precipitate is produced, copper not being thrown down
in presence of an alkaline cyanide. The precipitate of sulphide of
cadmium is separated from the solution by filtration, and the filtrate
saturated with hydrochloric acid. _Copper_, if present, is now
precipitated as sulphide: its separation is completed by conducting
sulphuretted hydrogen through the fluid.
The precipitate is collected, washed, dissolved in nitric acid, and its
identity established as previously directed. If the metal be present in
sufficient quantity, it should be obtained in a metallic state upon a
plate of iron; it is then coherent, possesses its natural color, and can
conveniently be exhibited to the Jury.
TREATMENT OF SOLUTION _b_.
This solution may contain: cobalt, nickel, iron, manganese, chromium,
zinc and aluminium. Of these, only zinc and chromium are poisonous; the
search for these two metals is therefore all that is necessary in
criminal cases. The solution is treated with a slight excess of ammonia,
sulphide of ammonium added, and the fluid, after being allowed to stand
for several hours, filtered. The precipitate may consist of sulphide of
zinc and hydrated oxide of chromium, as well as of traces of sulphide of
iron and phosphate of lime. If the suspected materials contained a
_chromate_, this salt, in presence of hydrochloric acid and sulphuretted
hydrogen, would be converted into sesquichloride of chromium a compound
which is precipitated by sulphide of ammonium as a hydrated oxide.
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