Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
Sulphates, chlorides, carbonates and phosphates are most frequently met
with in the preceding examination, and it should be carefully noticed
which of these salts exist in the greatest abundance. If acids of
comparatively rare occurrence (such as the oxalic and tartaric) are
found, their approximate amount is also to be noted. These facts,
together with the original acidity of the materials and the absence of
other toxical bodies, would lead to the conclusion that the poisoning
was caused by the reception of an acid, as well as to the identification
of the special acid used. In subsequently effecting the detection of the
poison by the determinative tests, the danger of destroying other
poisons possibly contained in the substance will be obviated, as the
question of the absence or presence of these latter will have been
previously decided.
(5). The examination for acids concluded, the various fluids which have
accumulated, and from which the acids present have been separated, are
united and the whole evaporated to dryness. The organic substances,
present in the residue obtained, are destroyed by means of nitric acid,
and the residual mass examined for _soda_. If this substance has not
been introduced into the portion of fluid examined, and is discovered in
a quantity largely in excess of the amount normally contained in the
organism, it is probable that poisoning has been caused by its
administration, and that an acid has also been given, either in order to
mask the poison, or to act as an antidote. In this case, it is necessary
to carefully search for acetic acid, as this is the substance usually
employed as an antidote for alkalies.
(6.) Whatever results have been obtained by the preceding examinations,
the portion of the fluid which has been treated with soda (_vide_ p.
87) is evaporated to dryness. The organic matters possibly present
are destroyed by means of nitric acid, or _aqua regia_, and the residue
taken up with water. The solution so obtained is then examined for
metals (including potassa, which salt has not been introduced into this
portion of the fluid in any of the preceding operations) by the usual
methods.
(7). The soluble portion of the suspected materials having been
thoroughly tested, the undissolved substances remaining on the filter
are next examined.
_b._ SOLID PORTION.
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