Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The mode of examination necessary when the hair has been blackened is
different from that used when it has been decolorized.
_The hair has been blackened._
As various methods of dyeing hair black are in use, the means of
restoring the original color differ. The following are the methods most
usually employed in dyeing:
1º. The hair is well rubbed with a pomade, in which finely pulverized
charcoal is incorporated. This preparation, which is sold under the name
of "_mélaïnocome_," possesses the disadvantage of soiling the fingers
and clothing, even for several days after its application.
2º. The hair is moistened with a dilute solution of ammonia, and a
perfectly neutral solution of a bismuth salt (chloride or nitrate) is
then applied. It is subsequently washed, and allowed to remain in
contact with a solution of sulphuretted hydrogen.
3º. The same operation is performed, a lead compound being substituted
for the bismuth salt.
4º. A mixture of litharge, chalk, and slacked lime is applied, and the
head covered with a warm cloth. The hair is afterwards washed, first
with dilute vinegar, then with the yolk of an egg.
5º. The hair is first cleansed with the yolk of an egg, and then
moistened with a solution of plumbate of lime; or,
6º. It is moistened with a solution of nitrate of silver, to which a
quantity of ammonia sufficient to dissolve the precipitate first formed
has been added.
The first method merely causes a mechanical admixture of a coloring
matter with the hair. In the four succeeding processes, a black metallic
sulphide is produced; either by the subsequent application of a solution
of sulphuretted hydrogen, or by the action of the sulphur normally
present in the hair.
In the last method, the formation of sulphide of silver doubtless
occurs; but the principal change that takes place is probably due to the
action of light, which, as is well known, decomposes the salts of
silver.
In order to restore the original color to hair which has been treated
with "_mélaïnocome_," it is only necessary to dissolve in ether the
fatty matters present, and then remove the charcoal by washing with
water.
In case the hair has been dyed by means of a bismuth or lead salt (as in
methods 2, 3, 4 and 5), it is immersed for several hours in dilute
hydrochloric acid: the metal present dissolves, as chloride, and the
original color of the hair is rendered apparent. It then remains to
detect the metal dissolved in the acid solution, in order to establish,
beyond doubt, the fact that a dye has been employed. This is
accomplished by means of the methods used for the detection of metals in
cases of supposed poisoning.
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