Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
EXAMINATION OF FIRE-ARMS.
(_Proposed by M. Boutigny._)
The examination of fire-arms is sometimes useful in determining the date
at which a weapon has been discharged or reloaded. The methods used in
examinations of this nature vary, as the weapon under inspection is one
provided with a flint or an ordinary percussion lock. The value of the
tests employed is also affected by the kind of powder used; _i. e._,
whether common gunpowder, gun-cotton or white gunpowder (prepared by
mixing yellow prussiate of potassa, chlorate of potassa and sugar) has
been taken.
THE GUN IS PROVIDED WITH A FLINT-LOCK, AND WAS CHARGED WITH ORDINARY
POWDER.
In case the weapon has been wiped or exposed to moisture subsequent to
its seizure, it is impossible to form any conclusion as to the date of
its discharge, etc. It is therefore advisable, upon receiving the
weapon, to carefully wrap the lock in a woollen cloth, and to close the
barrel. The exterior of the gun is at first submitted to a careful
examination, and notice taken of the approximate thickness of any
existing rust spots. The fire-pan and adjacent portion of the barrel are
also examined by aid of a magnifying glass, especial attention being
given to the detection of traces of a moist and pulverulent incrustation
of a greyish or blackish color, formed by the combustion of the
gunpowder, and of crystals of sulphate of iron. If the weapon is loaded,
the wad is withdrawn and the color of its cylindrical portion and of the
powder, as well as the size of the ball or shot, noted.
This preliminary examination ended, the barrel and fire-pan are
separately washed with distilled water, and the washings passed through
filter paper which has previously been well washed, first with pure
hydrochloric acid, then with distilled water. The filtrate is next
divided into three portions, and these separately examined for: (1)
sulphuric acid, by addition of chloride of barium; (2) for iron, by
oxidizing the salts contained in the fluid with a few drops of nitric
acid and adding a solution of ferrocyanide of potassium, the presence of
iron being indicated by the formation of a blue coloration, or a blue
precipitate; and (3) for sulphides, by means of a solution of subacetate
of lead.
If a bluish-black incrustation is discovered on the fire-pan or on the
neighboring portions of the barrel, and both rust and crystals of
sulphate of iron are absent, and the washings, which were originally of
a light-yellow color, assume a chocolate-brown coloration upon the
addition of solution of subacetate of lead, _the gun has been discharged
within two hours at the longest_.
If the incrustation possesses a lighter color and traces of iron have
been detected in the washings, but neither rust nor crystals have been
discovered on the barrel or fire-pan, _the weapon has been discharged
more than two, but less than twenty-four hours_.
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