Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
At present weapons having flint-locks have almost entirely gone out of
use and have been superseded by the ordinary percussion gun; these
latter, in turn, are being gradually replaced by breech-loaders, charged
with or without a metallic cartridge. The indications obtained in the
preceding examinations by means of the fire-pan, will therefore
disappear; the results given by the inspection of the barrel may
possibly hold good. In regard to breech-loaders, all the useful
indications furnished by the coloration of the wadding and powder fail
to occur; the latter being enclosed either in a paper cylinder or in a
copper socket.
The fact that gun cotton and white gunpowder are occasionally made use
of, adds to the difficulty of obtaining reliable results by the mere
inspection of a weapon. White gunpowder does not oxidize the gun, fails
to give rise to any salt of iron, and possesses a white color;
gun-cotton produces distinctive indications varying with its purity.
Owing to these facts, it is evident that the method proposed by M.
Boutigny is of no real value, save in the rare instances where a gun
provided with a fire-pan, and charged with ordinary powder, is under
examination, and the question of the lapse of time since the discharge
of a weapon must remain undetermined so far as scientific tests are
concerned.
DETECTION OF HUMAN REMAINS IN THE ASHES OF A FIRE-PLACE.
This class of examinations is particularly necessary when the crime of
infanticide is suspected. As the complete incineration of a cadaver is a
long and difficult operation, it frequently occurs that bones--partially
or completely carbonized, but retaining their original form--are
discovered by the careful examination of the ashes of the fire-place in
which the combustion was accomplished.
When this is not the case and complete incineration and disaggregation
have occurred, recourse must be had to the indications furnished by a
chemical analysis. These indications are reliable, however, only when
the certainty exists that bones of animals have not been consumed in the
same fire-place; otherwise, the results obtained are entirely worthless,
the reactions given by ashes of animal bones being identical with those
produced by the ashes of a human body. Two tests are employed to detect
the presence of bones in the residue left by the combustion of animal
matter.
1. A portion of the ashes is placed in a silver crucible, heated with
potassa, and the mass afterwards treated with cold water. If animal
matter is contained in the consumed materials, cyanide of potassium will
be present in the aqueous solution. In order to detect this salt, the
fluid is acidulated with hydrochloric acid, and a solution of
persulphate of iron added: the formation of a blue precipitate indicates
the presence of the cyanide.
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