Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
2. The ashes are next examined for phosphate of lime. As wood, coal, and
the other substances usually employed for heating purposes contain none
or little of this salt, its detection in a notable quantity would lead
to the inference that bones have been consumed. The ashes are allowed to
digest for twenty-four hours with one-quarter of their weight of
sulphuric acid. Water is next added to the pasty mixture, and the fluid
filtered. If phosphate of lime be present, it is converted by this
treatment into a soluble acid phosphate, which passes into the filtrate.
Upon adding ammonia to the filtrate, a precipitate of neutral phosphate
of lime is formed, neutral phosphate of ammonia remaining in solution.
The fluid is again filtered, the filtrate acidulated with nitric acid,
and then boiled with a solution of molybdate of ammonia likewise
acidulated with nitric acid: in presence of a phosphate, a yellow
precipitate, or at least a yellow coloration of the fluid, will be
produced. It has been stated that the disengagement of sulphuretted
hydrogen, upon treating the ashes with sulphuric acid, is an indication
that the combustion of a human body has occurred; this reaction is,
however, valueless, inasmuch as coal and certain vegetable ashes
likewise evolve the gas when subjected to the same treatment.
EXAMINATION OF WRITINGS.
Contracts, checks, etc., are frequently altered with criminal intent,
either by erasing the portion of the writing over the signature and
substituting other matter, or by changing certain words, in order to
modify the signification of a sentence.
Writings are altered either by erasure or by washing. Erasure, although
more easily executed, is seldom employed, as it renders the paper thin
in places, and in this way leaves effects apparent even to the naked
eye, and, although the original thickness can be restored by application
of sandarac or alum, these substances possess properties differing from
those exhibited by paper, and may, moreover, be completely removed, thus
exposing the thinning of the paper.
In case washing by means of chlorine has been resorted to, the
sizing--which renders the paper non-bibulous, and which is only with
difficulty replaced--may have been removed. Formerly paper was sized by
immersion in a solution of gelatine; at present, however, a soap of
resin, or wax, and alumina (a little starch being added) is more
commonly used. In the latter case, the sizing is less easily removed by
the action of water than when the gelatine preparation is employed; the
detection of its attempted restoration is also a matter of less
difficulty, as gelatine would be employed for this purpose, and this
body possesses properties different from those exhibited by the
substances normally contained in paper: iodine, for instance, which
imparts a yellow color to gelatine, turns starch violet-blue. In order
to detect the alteration of a writing, the following examinations are
made:
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