Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
In order to ascertain if a coin has been counterfeited, its weight
should at first be determined. If it has been clipped, or consists of an
alloy possessing a density less than that of silver or gold, the fact is
immediately demonstrated by its decreased gravity.
The coin is further tested by throwing it down upon a hard substance:
gold and silver give a ringing sound, whereas the majority of other
metals produce a dull sound.
The result obtained by this latter test often fails to be reliable. A
skilful counterfeiter may prepare an alloy equally sonorous and heavy as
silver or gold; in fact, _M. Duloz_ exhibited to the author an alloy,
prepared by him, possessing the density, sonorousness and lustre of
silver; the composition of which, for obvious reasons, has not been
published.
In instances of this nature the fusibility of the coin should be
determined, and the result obtained compared with the melting point of
the legal alloy, or, this failing, a chemical analysis executed. In
order to perform the latter test, the coin under examination is boiled
with nitric acid: all metals are dissolved, with exception of gold and
platinum, which remain unaltered, and tin and antimony, which are
converted respectively into metastannic and antimonic acids. The fluid
is filtered, the insoluble residue well washed, and then boiled with
hydrochloric acid, which dissolves the metastannic and antimonic acids.
The solution is again filtered, and the second residue dissolved in
_aqua regia_. The metals dissolved in the several filtrates are then
detected, either by the processes previously given for the detection of
metallic poisons, or by the more complete methods contained in works on
chemical analysis. This qualitative test is, however, insufficient, in
case the falsification consisted in merely diminishing the proportions
of the valuable metals contained in the alloy, without changing its
qualitative composition: it is then necessary to execute a quantitative
estimation of the metals present. As this operation requires
considerable practice and the methods employed are to be found in all
treatises on quantitative analysis, we will not reproduce them here.
EXAMINATION OF ALIMENTARY AND PHARMACEUTICAL SUBSTANCES.
We will next enumerate the methods employed in the detection of the
principal adulterations to which flour, bread, oils of seeds, milk,
wines, vinegar and the sulphate of quinine are subjected. These
researches, united with those preceding, fail to embrace all the diverse
examinations which the chemical expert may be expected to execute; but
we do not claim to foresee all the contingencies that may arise, and
will describe the steps to be pursued in instances which are
anticipated, at the same time indicating general methods applicable to
cases not here included.
FLOUR AND BREAD.
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