Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
2. The paper is exposed to the action of steam, in order to moisten the
ink present (care being taken to avoid dissolving the characters), and a
current of sulphuretted hydrogen allowed to act upon it. If the ink used
consists of a lead, bismuth, or gold salt, a black coloration will
ensue; if salts of cadmium or arsenic were employed, the characters will
acquire a yellow color; if, finally, a salt of antimony was used, a red
coloration will be produced.
3. If no coloration was caused by the action of sulphuretted hydrogen,
it is probably that either a solution of ferrocyanide of potassium or a
persalt of iron has been resorted to. Each of these solutions is
separately applied on a small portion of paper by means of a brush, and
notice taken if the characters become visible. The solution that
produced the change is then applied over the entire sheet.
4. In case only negative results were obtained in the preceding
operations, it must not yet be concluded that a sympathetic ink has not
been used, although we are left without further recourse to chemical
tests. Numerous organic compounds may have been resorted to, the
detection of which is almost impossible; moreover, if a mistake was made
in regard to the preparation supposed to have been used, the reagents
employed for its detection may render the discovery of another ink
absolutely impossible. It is therefore often necessary to apply
mechanical tests. For this purpose, the paper is spread upon a glass
plate, uniformly moistened with water, and a second plate placed over
it: if the characters were written with a pulverulent substance
suspended in water or mucilage, they may often be observed upon
examining the transparency of the paper. In case the substance used is
both colorless and soluble, the detection of the written characters will
be more difficult; still, indelible traces may possibly have been left
by the pen. If, however, the ink employed is a colorless and transparent
organic compound of rare occurrence, and was applied with a fine
pencil-brush which failed to affect the paper, it must be acknowledged
that little or nothing can be definitely determined as to its presence
or absence.
FALSIFICATION OF COINS AND ALLOYS.
In all civilized countries a fixed standard for coins and precious
alloys is established by law, in order to prevent the perpetration of
frauds which would be of serious injury to the public welfare. The
substitution of coins consisting of an alloy inferior in value to the
standard fixed by law, is too advantageous a fraud not to be often
attempted.
Coins are most frequently altered by _clipping_; by _stuffing_, that is,
by boring the coin and inserting an alloy of small value; by _doubling_,
which operation consists in covering its face with two thin laminæ taken
from a genuine coin; and by applying a coating of gold or silver by
means of electro-plating.
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