Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The table below may prove useful as indicating the requirements to be
exacted when the chemist is asked to give an opinion concerning the
presence of facing admixtures or of exhausted or foreign leaves in a
sample of tea:
_Total ash_--should not be under 4.5% or over 7%.
_Ash soluble in water_--should not be under 40% of total ash.
_Ash insoluble in water_--should not be over 3%.
_Ash insoluble in acid_--should not be over 1%.
_Extract_--should not be under 30%.
_Insoluble leaf_--should not be over 60%.
NOTE.--The British Society of Public Analysts adopt:
_Total Ash_ (dry basis)--not over 8% (at least 3% should be soluble in
water).
_Extract_ (tea as sold)--not under 30%.
MILK.
The chief constituents of milk are water, butter, caseine, lactose
(milk-sugar), traces of albumen and mineral salts. Butter is present in
the form of minute globules, held in suspension; the caseine, for the
greater part, is in solution, only a small portion being present in an
insoluble suspended condition. In milk only a few days old, the
_colostrum_ (the milk secreted during the first few days after
parturition) consists largely of rather voluminous cellular
conglomerations, containing a sufficient quantity of albumen to
coagulate upon heating.
The normal density of milk is 1.030, water being 1.000; the density
rising to 1.036, if the fluid has been skimmed.
Good milk contains, on an average, 3.7 per cent. of butter; 5.7 per
cent. of lactose, and leaves upon evaporation 12 to 14 per cent. of
solid matters.[T] The most common adulteration of milk consists in the
addition of water. This fraud is detected by means of an areometer
(_lactodensimeter_) which gives directly the specific gravity of the
fluid under examination. Should the density be much below 1.030, it is
certain that water has been added. It does not, however, necessarily
follow if it is about 1.030 that the milk is pure, since the gravity of
the fluid, which would be increased upon skimming, could be subsequently
reduced to 1.030 by the addition of water. The lactodensimeter,
therefore, although useful in the detection of a simple admixture, fails
to give reliable results if the fraud perpetrated is a double one; and a
determination of the proportion of butter present is also usually
necessary. Numerous methods have been proposed to accomplish this
estimation. The most preferable of these, owing to the rapidity with
which the operation is executed, is the use of the lactoscope
(_galactoscope_). This instrument consists of a tube provided with a
glass plate fitted at one end, and with a movable glass plate at the
other extremity. A few drops of the milk to be tested are placed between
the two plates, and the tube lengthened, by screwing out the movable
plate, until the fluid no longer transmits the light of a candle placed
at a distance of one metre. As the opacity of milk is due to the butter
present, it is evident that the proportion of this substance contained
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