Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
_Emulsion of almonds._--The milk has a specific gravity of at least,
1.033. If it is passed through a gauze, small opaque lumps are
separated. When examined under the microscope, numerous minute globules,
having a diameter of 1/400 of a millimetre, are observed, and, upon
adding a few centigrammes of amygdaline to one or two grammes of the
milk, the characteristic odor of bitter almonds is produced.
_Gum tragacanth._--When shaken in a glass flask and allowed to rest, the
milk deposits on the sides small transparent lumps, which usually
present a slightly elongated or angular form.
_Gum arabic._--The addition of alcohol produces an abundant white opaque
precipitate.
_Starch, flour, decoction of barley, rice, etc._--Upon boiling the
suspected milk, and adding tincture of iodine, the amylaceous substances
present produce a blue coloration in the fluid.
_Sugar._--If yeast is added, and the mixture allowed to stand for some
time at a temperature of 30°, alcoholic fermentation ensues; under these
circumstances, lactose does not undergo fermentation.
_Cerebral substances._--Adulteration by these substances is probably of
much less frequent occurrence than was formerly supposed. The admixture
is detected by evaporating the milk to dryness, dissolving the residue
in ether, evaporating the etherial solution, and fusing the second
residue, which consists of fatty matters, with nitrate of potassa in a
platinum crucible. The mass is then taken up with water, and chloride of
barium added to the solution. If cerebral substances were contained in
the milk, ether will dissolve the fatty matters present, the phosphorus
of which is converted into a soluble phosphate by the calcination with
nitrate of potassa and is thrown down as a white precipitate, upon the
addition of a solution of chloride of barium. This test may be confirmed
by a microscopic examination of the milk, when the peculiar appearance
of cerebral matter will be detected.[U]
[U] Fragments of nerves, and other organic structures, are frequently
observed in this examination.--_Trans._
WINE.
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