Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The most common adulteration to which wines are subjected is the
addition of water: wines having a rich color are frequently mixed by the
dealer with lighter wines, and the fraud consummated by adding water.
The detection of this adulteration is somewhat difficult, as water is a
normal constituent of wine. In Paris the following method is usually
employed: As soon as the wine is confiscated, it is ascertained what
kinds of wine are manufactured by the inculpated dealer, and a statement
obtained from him, giving the proportions of alcohol, etc., contained in
the various brands. A wine is then prepared, according to the
information received, an estimation of the alcohol contained in the
prepared sample made, and the results compared with those furnished by a
similar examination of the suspected wine. In case the proportion of
alcohol is less in the suspected wine than in the prepared sample, it is
evident that a fraudulent adulteration has been committed. If, however,
the quantity of alcohol is the same in both wines, it does not
necessarily follow that the wine has escaped admixture, since this body
may have been added after the adulteration with water. In addition to
the estimation of alcohol, it is also necessary to determine the amount
of cream of tartar (bitartrate of potassa) present, as the proportion of
this salt would be sensibly decreased by the addition of alcohol and
water to the wine. This fraud could, however, be disguised by
subsequently adding the proper amount of cream of tartar.
It is also well to ascertain if two equal quantities of the prepared
sample and the wine under examination require the same amount of
solution of hypochlorite of lime for decolorization. In case the
suspected wine has been adulterated, the quantity of hypochlorite
solution used will be less than the amount necessary to decolorize the
prepared wine. Foreign coloring matter may be added by the adulterator,
but this fraud is easily detected by adding potassa to the sample: if
its coloration is natural, a green tint is produced; whereas, if foreign
matter has been introduced, the wine assumes various other colors upon
the addition of the alkali.[V]
[V] _Cotlini_ (_Ann. du genie civil_, No. 3, 1873) states that the
following reactions occur when artificially colored wines are heated
with potassa:
Pure wine no precipitate greenish hue
Elderberry violet "
Beet-sugar red "
Logwood red violet-red "
Privet violet-blue "
Turmeric light-blue "
According to _M. de Cherville_ (_Quar. Jour. Sc._), a bright violet
coloration is produced in the above test, if litmus be present.
Fuchsin is separated by treatment with subacetate of lead and
addition of amylic alcohol (_Jour. de Ph. et de Ch. Mar.
1873_).--_Trans._
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