Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
_g._ Solutions of the alkalies, which dissolve the albumen, leave the
coloring matters intact, and consequently do not decolorize the fabric.
If the latter is afterwards subjected to the action of hydrochloric
acid, the coloring matter is dissolved, forming a solution that leaves
upon evaporation to dryness a residue containing iron, which gives a
blue coloration with ferrocyanide of potassium, and a red coloration
with sulphocyanide of potassium.
_h._ The coloring matter of blood dissolves in boiling alcohol, to which
sulphuric acid has been added, to a brown dichroic fluid (appearing
green by transmitted light, and red by reflected light). A mixture of
rust and blood exhibits the same phenomenon.
_i._ If substances containing blood are heated in a dry tube, an odor
resembling that of burnt horn is emitted. In case the stained fabric is
a substance that would produce this odor, (such as wool, silk, or hair),
the test naturally loses all value.
_j._ If the fluid obtained by treating the stains either with water or
alkali is evaporated with a little carbonate of potassa, and the residue
heated, at first at 100°, then to redness, in a glass tube to which a
fresh quantity of carbonate of potassa has been added, cyanide of
potassium is formed. When cold, the tube is cut above the part
containing the fused mixture, the mass heated with iron-filings and
water, the fluid filtered, and the filtrate then acidulated with
hydrochloric acid: ferrocyanide of potassium will be present in the
fluid, and upon adding a drop of solution of perchloride of iron a
green, or blue, color will be produced, and a precipitate of Prussian
blue gradually thrown down.
If the stained cloth is non-nitrogenous (_per ex._: hemp, linen, or
cotton), instead of treating it with water, it may be heated until
pulverulent, mixed with carbonate of potassa, the mixture calcined, and
the operation then completed as just described. This test having given
affirmative results, the operations should be repeated with an unstained
portion of the cloth, to remove all doubt that the indications obtained
do not really originate from the fabric.
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