Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
In the present state of science, it is impossible to discriminate
chemically between human and animal blood. _M. Barruel_, it is true, is
able, not only to accomplish this, but also to distinguish the blood of
the various species of animals by its odor! But this test has a somewhat
hypothetical value for scientific purposes. In regard to the crystals of
haemin, they do not present sufficient difference to allow the blood of
different animals to be distinguished. We have not yet treated of the
globules. It often occurs that these minute organs are so altered as to
be no longer recognized in the microscopic examination; when, however,
the stains are tolerably recent, they may be detected by examining the
moistened stained cloth, directly under the microscope: a discrimination
between animal and human blood is then possible: corpuscules of human
blood possess the greater size: those of the sheep, for instance, have
only one-half the diameter of the former. It is, however, but seldom
that this distinction can be made use of.[Y]
[Y] _Menstrual blood_ is recognized by the presence of epithelial
cells.--_Trans._
EXAMINATION OF SPERMATIC STAINS.
In cases where attempt at violence, rape or pederasty is suspected, the
expert may be required to determine the nature of stains found on
clothing, sheets, etc. The fact that the stains were produced by semen,
may often be regarded, _per se_, as criminating evidence. This class of
investigation possesses, therefore, considerable importance.
_External appearance of the stains._--Dry spermatic stains are thin, and
exhibit a greyish or, occasionally, a citron-yellow color, if present on
white cloth. In case the fabric is colored, they appear whitish and, if
on linen, present a glossy aspect. They are translucid, when observed by
transmitted light. If the fabric, upon which the stains are deposited,
is of a heavy texture, they are visible only on one side: under all
circumstances, their circumference is irregular and undulated. These
indications, however, are not conclusive, but vary according to whether
the stains were produced by the thick semen of a vigorous man, or the
aqueous seminal fluid of an aged and diseased person, or by semen more
or less mixed with the prostatic fluid. Upon moistening spermatic
stains, the distinctive stale odor of fresh semen is sometimes emitted,
but this characteristic is usually obscured by the presence of foreign
substances.
Semen stains are soluble in water, forming a gummy fluid, in which
chlorine, alcohol, bichloride of mercury, acetate and subacetate of lead
produce a white precipitate, but which fails to be coagulated by
heating. Plumbate of potassa does not impart a fawn-color to these
stains, at a temperature above 20°, as is the case with those produced
by albuminous substances.
Persulphate of iron imparts to spermatic stains a pale yellow color,
Sulphate of copper, a bluish grey color,
Cupro-potassic tartrate, a bluish grey color,
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