Letters of a Radio-Engineer to His Son — John Shaqi
Letters of a Radio-Engineer to His SonMills, John
Philosophy
Letters of a Radio-Engineer to His Son
Mills, John
Radio
When silver nitrate molecules go into solution they break up into ions
just as copper sulphate does. One ion is a silver atom which has lost
one electron. This electron was stolen from it by the nitrate part of
the molecule when they dissociated. The nitrate ion, therefore, is
formed by a nitrogen atom, three oxygen atoms, and one extra electron.
If we put two plates of silver into such a solution nothing will happen
until we connect a battery to the plates. Then the battery takes
electrons away from one plate and gives electrons to the other. Some of
the atoms in the plate which the battery is robbing of electrons are
just like the silver ions which are moving around in the solution.
That's why they can go out into the solution and play with the nitrate
ions each of which has an extra electron which it stole from some silver
atom. But the moment silver ions leave their plate we have more silver
ions in the solution than we do sulphate ions.
The only thing that can happen is for some of the silver ions to get out
of the solution. They aren't going back to the positive silver plate
from which they just came. They go on toward the negative plate where
the battery is sending an electron for every one which it takes away
from the positive plate. There start off towards the negative plate, not
only the ions which just came from the positive plate, but all the ions
that are in the solution. The first one to arrive gets an electron but
it can't take it away from the silver plate. And why should it? As soon
as it has got this electron it is again a normal silver atom. So it
stays with the other atoms in the silver plate. That's what happens
right along. For every atom which is lost from the positive plate there
is one added to the negative plate. The silver of the positive plate
gradually wastes away and the negative plate gradually gets an extra
coating of silver.
Every time the battery takes an electron away from the positive plate
and gives it to the negative plate there is added to the negative plate
an atom of silver. If the negative plate is weighed before the battery
is connected and again after the battery is disconnected we can tell how
much silver has been added to it. Suppose the current has been perfectly
steady, that is, the same number of electrons streaming through the
circuit each second. Then if we know how long the current has been
running we can tell how much silver has been deposited each second.
The law says that if silver is being deposited at the rate of 0.001118
gram each second then the current is one ampere. That's a small amount
of silver, only about a thousandth part of a gram, and you know that it
takes 28.35 grams to make an ounce. It's a very small amount of silver
but it's an enormous number of atoms. How many? Six billion billion, of
course, for there is deposited one atom for each electron in the stream.
Public-domain text, read in full here on John Shaqi.
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