_Influence of Mechanical Pressure._—Mechanical pressure is also capable
of causing one metal to pass into another. We need not recall the
well-known experiment of Cailletet, who, by employing considerable
pressure, caused mercury to sweat through a block of iron. In a more
simple manner W. Spring showed that a disc of copper could be welded
to a disc of tin by pressing them strongly one against the other. Up to
a certain distance from the surfaces of contact a real alloy is formed;
a layer of bronze of a certain thickness unites the two metals, and
this could not take place did not the particles of both metals mutually
interpenetrate.
§ 4. INTERNAL ACTIVITY OF ALLOYS.
_Structure of Alloys._—Metallic alloys have a remarkable structure,
which is essentially mobile, and which we have only now begun to
understand by the aid of the microscope. Microscopical examination
justifies to a certain degree Coulomb’s conjecture. That illustrious
physicist explained the physical properties of metals by imagining them
to be formed of two kinds of elements—integral particles, to which
the metal owes its elastic properties, and a _cement_ which binds the
particles, and to which it owes its coherence. M. Brillouin has also
taken up this hypothesis of duality of structure. The metal is supposed
to be formed of very small, isolated, crystalline grains, embedded in
an almost continuous network of viscous matter. A more or less compact
mass surrounding more or less distinct crystals is the conception which
may be formed of an alloy.
_Changes of Structure produced by Deforming Agencies._—It has been
shown that profound changes of crystalline structure can be produced
by various mechanical means, such as hammering, and the stretching
of metallic bars carried to the point of rupture. Some of these
changes are very slow, and it is only after months and years that
they are completed, and the metal attains the definite equilibrium
corresponding to the conditions to which it is exposed. Though there
may be discussions concerning the extent of the transformations to
which it is subjected, though some believe they affect the chemical
condition of the alloy, while others limit its power to physical
effects, it is nevertheless true—and this brings us back to our
subject—that the mass of these metals is at work, and that it only
slowly attains the phase of complete repose.
_The Slow Re-establishment of Equilibrium. Residual Effect._—These
operations by which the physical characters of metals are changed, and
by which they are adapted to a variety of industrial needs—compression,
hammering, rolling, stretching, and torsion—have an immediate, very
apparent effect; but they have also a consecutive effect, slowly
produced, much less marked and less evident. This is the “residual
effect,” or “Nachwirkung” of the Germans. It is not without importance,
even in practical applications.
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