Heat also creates a kind of _forced equilibrium_. This becomes but
slowly modified, so that a body may remain for a long time in a state
which is, however, not the most stable for the conditions under which
it is considered. The number of these bodies _not in equilibrium_ is as
great as that of the substances which have been exposed to fusion. All
the Plutonic rocks are in this condition. Glass presents a condition of
the same kind. Thermometers placed in melting ice do not always mark
the zero Centigrade. This displacement of the zero point falsifies all
records if care is not taken to correct it. The correction usually
requires prolonged observation. The theory of the displacement of the
thermometric zero is not entirely established; but we may suppose,
with the author of the _Traité de Thermométrie_, that in glass, as
in alloys, are to be found compounds which vary according to the
temperature. At each temperature glass tends to assume a determinate
composition and a corresponding state of equilibrium; but the previous
temperature to which it has been subjected clearly has an influence
on the rapidity with which it attains its state of repose. The effect
of variation is more marked when we observe glass of more complicated
composition. We can understand that those which contain comparable
quantities of the two alkalies, soda and potash, may be more subject to
these modifications than those having a more simple composition based
on a single alkali.
_Effects of Annealing._—A piece of brass wire that has been drawn and
then heated is the scene of certain very remarkable internal changes,
and these have been only recently recognized. The violent treatment
of the metallic thread in forcing it through the hole in the die has
crushed the crystalline particles; the interior state of the wire is
that of broken crystals embedded in a granular mass. Heating changes
all that. The crystals separate, repair themselves, and are built
up again; they are then hard, geometrical bodies, in an amorphous,
relatively soft and plastic mass; their number keeps on increasing;
equilibrium is not established until the entire mass is crystallized.
We may imagine how many displacements, enormous when compared with
their dimensions, the molecules have to undergo when passing through
the resisting mass, and arranging themselves in definite places in the
crystalline structures.
In the same way, too, in the manufacture of steel, the particles of
coal at first applied to the surface pass through the iron.
This _faculty of molecular displacement_ enables the metal in some
cases to modify its state at one point or another. The use made of this
faculty under certain circumstances is very curious, greatly resembling
the adaptation of an animal to its environment, or the methods of
defence against agents that might destroy it.
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