Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
Now let us examine some of the shapes which drops actually assume. I
take a glass plate covered with a thin layer of grease, which prevents
adhesion of water to the glass, and form upon it drops of water of
various sizes by the aid of a pipette. You see them projected on the
screen (Fig. 4). The larger drops are flattened above and below, but
possess rounded sides and resemble a teacake in shape. Those of
intermediate size are more globular, but still show signs of flattening;
whilst the very small ones, so far as the eye can judge, are spherical.
Evidently, the shape depends upon the size; and this calls for some
explanation. If we take a balloon of indiarubber filled with water, and
rest it on a table, the weight of the enclosed water will naturally tend
to stretch the balloon sideways, and so to flatten it. A smaller
balloon, made of rubber of the same strength, will not be stretched so
much, as the weight of the enclosed water would be less; and if the
balloon were very small, but still had walls of the same strength, the
weight of the enclosed water would be incompetent to produce any visible
distortion. It is evident, however, that so long as it is under the
influence of gravitation, even the smallest drop cannot be truly
spherical, but will be slightly flattened. The tendency of drops to
become spherical, however, is always present.
[Illustration: __Fig._ 5.—Formation of a sphere of orthotoluidine._]
*Production of True Spheres of Liquids.*—Now it is quite possible to
produce true spheres of liquid, even of large size, if we cancel the
effect of gravity; and we may obtain a hint as to how this may be
accomplished by considering the case of a soap-bubble, which, when
floating in air, is spherical in shape. Such a bubble is merely a skin
of liquid enclosing air; but being surrounded by air of the same
density, there is no tendency for the bubble to distort, nor would it
fall to the ground were it not for the weight of the extremely thin
skin. The downward pull of gravity on the air inside the bubble is
balanced by the buoyancy of the outside air; and hence the skin,
unhampered by any extraneous force, assumes and retains the spherical
form. And similarly, if we can arrange to surround a drop of liquid by a
medium of the same density, it will in turn become a sphere. Evidently
the medium used must not mix with the liquid composing the drop, as it
would then be impossible to establish a boundary surface between the
two. Plateau, many years ago, produced liquid spheres in this manner. He
prepared a mixture of alcohol and water exactly equal in density to
olive oil, and discharged the oil into the mixture, the buoyancy of
which exactly counteracted the effect of gravity on the oil, and hence
spheres were formed. The preparation of an alcohol-water mixture of
exactly correct density is a tedious process, and we are now able to
dispense with it and form true spheres in a more convenient way. There
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