Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
*The “Diving” Drop.*—In order to illustrate the tension at the boundary
surface of two liquids, I now show an experiment in which a drop is
forcibly projected downwards by the operation of this tension. I pour
some water into a narrow glass vessel, and float upon it a liquid called
_dimethyl-aniline_, so as to form a layer about 1 inch in depth. A glass
tube, open at both ends, is now passed down the floating liquid into the
water, and then raised gradually, with the result that a skin of water
adheres to the end, and is inflated by the upper liquid, forming a
sphere on the end of the tube (Fig. 10). On withdrawing the tube from
the upper surface, the sphere is detached and falls to the boundary
surface, where it rests for a few seconds, and is then suddenly shot
downwards into the water (Figs. 11 and 12). It then rises to the
interface; breaks through, and mingles with the floating liquid, thereby
losing its identity. Why should the drop, which is less dense than
water, dive below in this manner? The explanation is that the drop
(which consists of a skin of water filled with dimethyl-aniline), after
resting for a time on the joining surface, loses the under part of its
skin, which merges into the water below. The shape of the boundary of
the two liquids is thereby altered, the sides now being continuous with
the skin forming the upper part of the drop. This is an unstable shape;
and accordingly the boundary surface flattens to its normal condition,
and with such force as to cause the drop beneath it to dive into the
water, although the liquid is lighter than water and tends to float. The
result is the same as that which would occur if a marble were pressed on
to a stretched disc of rubber, and then released, when it would be
projected upwards owing to the straightening of the disc. I now repeat
the experiment, using paraffin oil instead of dimethyl-aniline; but in
this case the drop is only projected to a small depth, and the effect is
not so marked. The experiment furnishes conclusive evidence of the
existence of the interfacial tension.
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