Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
A liquid issuing from a tube is pulled downwards by the force of
gravitation, and therefore is always tending to fall. At first, when the
drop is small, the action of gravity is overcome by the surface tension
of the liquid; but as the drop grows in size and increases in weight, a
point arrives at which the surface tension is overpowered. Then
commences the formation of a neck, which grows narrower under the
stretching force exerted by the weight of the drop, until rupture takes
place. Now if we wish to make the process more gradual, it will be
necessary to reduce the effect of gravity, as we cannot increase the
surface tension. We have already seen how this may be done in connexion
with liquid spheres—indeed, we were able to cancel the influence of
gravity entirely, by surrounding the working liquid by a second liquid
of exactly equal density. We require now, however, to allow the downward
pull of the drop ultimately to overcome the surface tension, and we must
therefore form the drop in a less dense liquid. If this surrounding
liquid be only slightly less dense, we should be able to produce a very
large drop; and if we make its growth slow we may observe the whole
process of formation and separation with the unaided eye.
[Illustration: __Fig._ 13.—Apparatus for forming ascending or descending
drops of liquids._]
Now it so happens that we have to hand two liquids which, without any
preparation, fulfil our requirements. Orthotoluidine, at temperatures
below 75° F. or 24° C., is denser than water of equal temperature. At
75° F. their densities are identical; and as the ordinary temperature of
a room lies between 60° and 70° F., water, under the prevailing
conditions, will be slightly the less dense of the two, and will
therefore form a suitable medium in which to form a large drop of
orthotoluidine. I therefore run this red-coloured liquid into water from
a funnel controlled by a tap (Fig. 13), and in order to make a large
drop the end of the stem is widened to a diameter of 1½ inches. It is
best, when starting, to place the end of the stem in contact with the
surface of the water, as the first quantity of orthotoluidine which runs
down then spreads over the surface and attaches itself to the rim of the
widened end of the stem. The tap is regulated so that the liquid flows
out slowly, and we may now watch the formation of the drop. At first it
is nearly hemispherical in shape; gradually, as you see, it becomes more
elongated; now the part near the top commences to narrow, forming a
neck, which, under the growing weight of the lower portion, is stretched
until it breaks, setting the large drop free (Figs. 14 to 18). And then
follows the droplet; very small by comparison with the big drop, but
plainly visible (Figs. 19 and 20). The graceful outline of the drop at
all stages of the formation must appeal to all who possess an eye for
beauty in form; free-flowing curves that no artist could surpass,
Public-domain text, read in full here on John Shaqi.
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