Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
In our previous experiments we have seen that in order to produce large
drops of a given liquid, the surroundings should be of nearly the same
density, so as largely to diminish the effective weight of the suspended
mass. We might therefore expect that large columns of liquid could be
produced under similar conditions; and our conjecture is correct. We
may, for example, use the apparatus by means of which large drops of
orthotoluidine were formed (Fig. 13), using a shallow layer of water, so
that the lower end of the drop would come into contact with the bottom
of the vessel before the breaking stage was reached, and thus produce,
on a large scale, the same result as that we have just achieved by
allowing a hanging drop of water to touch a glass plate. This method,
however, restricts the diameter of the top of the column to that of the
delivery tube, and in this respect the shape is strained. The remedy for
this is to hang the drop from the surface of the water, when a degree of
freedom is conferred upon the upper part, which enables the column to
assume a greater variety of shapes. In order to show how this may be
accomplished, I pour a small quantity of water into the rounded end of a
wide test-tube, which is now seen projected on the screen, and then pour
gently down the side a quantity of _ethyl benzoate_, a liquid slightly
denser than water. You observe that the liquid spreads out on the
surface of the water, forming a hanging drop which at first is nearly
hemispherical in shape; but as I continue to add the liquid the drop
grows in size downwards, and finally reaches the bottom of the tube.
There is our liquid column (Fig. 27), which has formed itself in its own
way, free from the restriction imposed by a delivery tube. Notice the
graceful curved outline, produced by a beautiful balance between the
forces of surface tension and gravitation; and notice also how the
outline may be varied by the gradual addition of water, which causes the
upper surface to rise, and thus stretches the column (Fig. 28). The
middle becomes more and more narrow (Fig. 29), and finally breaks
across, leaving a portion of the former column hanging from the surface,
and the remainder, in rounded form (Fig. 30), at the bottom of the tube.
And, as usual, the partition was accompanied by the formation of a small
droplet.
[Illustration: __Figs._ 27, 28, 29, 30.—A liquid column stretched
upwards until broken by addition of water. Four stages._]
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