Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
direction of flow, which we succeeded in accomplishing with liquid drops
formed in a medium of slightly inferior density.
[Illustration: __Fig._ 33.—Combined drops of vapour and liquid._]
*Combined Vapour and Liquid Drops.*—All liquids when heated give off
vapour, the amount increasing as the temperature rises. The vapour
formed in the lower part of the vessel in which the liquid is heated
rises in the form of bubbles, which may condense again if the upper part
of the liquid be cold. When the liquid becomes hot throughout, however,
the vapour bubbles reach the surface and break, allowing the contents to
escape into the air above. Everyone who has watched a liquid boiling
will be familiar with this process, but it should be remembered that a
liquid may give off large quantities of vapour without actually boiling.
A dish of cold water, if exposed to the air, will gradually evaporate
away; whilst other liquids, such as petrol and alcohol, will disappear
rapidly under the same circumstances—and hence are called “volatile”
liquids.
The formation of vapour and its subsequent escape at the surface of the
liquid, enable us to produce a very novel kind of drop; if, instead of
allowing the bubbles to escape into air, we cause them to enter a second
liquid. Here, for example, is a coloured layer of chloroform¹ at the
bottom of a beaker, with a column of water above. I project the image of
the beaker on the screen, and then heat it below. The chloroform vapour
escapes in bubbles; but notice that each bubble carries with it a
quantity of liquid, torn off, as it were, at the moment of separation.
The vapour bubbles and their liquid appendages vary in size, but some of
them, you observe, have an average density about equal to that of the
water, and float about like weighted balloons. Some rise nearly to the
surface, where the water is coldest; and then the vapour partially
condenses, with the result that its lifting power is diminished, and
hence the drops sink into the lower part of the beaker. But the water is
warmer in this region, and consequently the vapour bubble increases in
size and lifting power until again able to lift its load to the surface.
So the composite drops go up and down, until finally they reach the
surface, when the vapour passes into the air, and the suspended liquid
falls back to the mass at the bottom of the beaker. Notice that the drop
of liquid attached to each bubble is elongated vertically. This is
because chloroform is a much denser liquid than water (Fig. 33). There
is a practical lesson to be drawn from this experiment. Whenever a
bubble of vapour breaks through the surface of a liquid, it tends to
carry with it some of the liquid, which is dragged mechanically into the
space above. In our experiment the space was occupied by water, which
enabled the bubble to detach a much greater weight than would be
possible if the surface of escape had been covered by air, which is far
less buoyant than water.
Public-domain text, read in full here on John Shaqi.
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