Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
*Movements of Orthotoluidine and Xylidine 1-3-4 on a Water Surface.*—We
will now observe, by the aid of the lantern, movements of globules more
striking, and certainly more puzzling, than those of aniline. I place on
the surface of the water a quantity of a special sample of
orthotoluidine, and you see that immediately a number of globules are
formed which are endowed with remarkable activity. They become indented
at one side, and then dart across the surface at a great speed, usually
breaking into two as a result of the violent action (Fig. 37). Then
follows a short period of rest, when suddenly, as if in response to a
signal, all the larger globules again become indented, forming shapes
like kidneys, and again shoot across the surface, breaking up into
smaller globules. Notice that the very small globules remain at rest; it
is only those above a certain size that display this remarkable
activity. A film of the liquid forms on the water, and the action
gradually becomes more intermittent, ceasing altogether when a skin is
well established, and the large globules have sub-divided into very
small ones. My sample of orthotoluidine is somewhat unique, as other
specimens of the liquid, obtained from the same and other sources, do
not show the same lively characteristics. As in the case of camphor,
touching the surface with a drop of oil arrests the movements
immediately. The organic liquid _xylidine_ 1-3-4, however, exhibits the
same movements, as you now see on the screen; and, if anything, is even
more active than the orthotoluidine previously shown. It may be added
that occasional samples of aniline show similar movements, but of less
intensity.
Now if I am asked to explain these extraordinary movements, I am bound
to confess my inability to do so at present. Why should the globules
become indented on one side only? The two tensions acting at the edge in
opposition to the water tension are at work all round the globule, and
it is not easy to see why they should prevail to such a marked degree at
one spot only. The movement across the surface, if we followed our
previous explanations, would be due to the superior pull of the water
tension behind the globule, opposite the indented part; although to look
at it would seem as if some single force produced the indentation and
pushed the globule along bodily. Are there local weaknesses in the
tension of the water, and, if so, why should such weak spots form
simultaneously near each globule, causing each to move at the same
moment? Any explanation we may give as to the origin of the cavity in
the side of the globule does not suffice to account for the intermittent
character of the movement, and its simultaneous occurrence over the
whole surface. We must therefore leave the problem at present, and trust
to future investigation to provide a solution.
[Illustration: __FIG. 38._—Resolution of a floating skin into
globules._]
Public-domain text, read in full here on John Shaqi.
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences — John Shaqi
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