Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiencesDarling, Charles R. (Charles Robert)
Science
Liquid Drops and Globules, Their Formation and Movements: Three lectures delivered to popular audiences
Darling, Charles R. (Charles Robert)
Drops; Liquids; Surface tension
*Boundary Surface of two Liquids.*—So far we have been considering
surfaces bounded by air, or—in the case of the alcohol thermometer—by
vapour. It is possible, however, for the surface of one liquid to be
bounded by a second liquid, provided the two do not mix. We may, for
example, pour petroleum on to water, when the top of the water will be
in contact with the floating oil. If now we lower our piece of silver
foil through the petroleum, and allow it to reach the surface of the
water, we find that the elastic skin is still capable of sustaining the
weight; and thus we see that the elastic layer is present at the
junction of the two liquids. What is true of water and oil in this
respect also holds good for the boundary or interface of any two liquids
which do not mix. Evidently, if the two liquids intermingled, there
would be no definite boundary between them; and this would be the case
with water and alcohol, for example.
*Area of Stretched Surface.*—We will not at present discuss the nature
of the forces which give rise to this remarkable property of a liquid
surface, but will consider one of the effects. The tendency, as in the
case of all stretched membranes, will be to reduce the area of the
surface to a minimum. If we take a disc of stretched indiarubber and
place a weight upon it, we cause a depression which increases the area
of the surface. But on removing the weight, the disc immediately
flattens out, and the surface is restored to its original smallest
dimension. Now, in practice, the surface of a liquid is frequently
prevented from attaining the smallest possible area, owing to the
contrary action of superior forces; but the tendency is always manifest,
and when the opposing forces are absent or balanced the surface always
possesses the minimum size. A simple experiment will serve to illustrate
this point. I dip a glass rod into treacle or “golden syrup,” and
withdraw it with a small quantity of the syrup adhering to the end. I
then hold the rod with the smeared end downwards, and the syrup falls
from it slowly in the form of a long, tapered column. When the column
has become very thin, however, owing to the diminished supply of syrup
from the rod, we notice that it breaks across, and the upper portion
then shrinks upwards and remains attached to the rod in the form of a
small drop (Fig. 3). So long as the column was thick, the tendency of
the surface layer to reduce its area to the smallest dimensions was
overpowered by gravity; but when the column became thin, and
consequently less in weight, the elastic force of the outer surface was
strong enough to overcome gravitation, and the column was therefore
lifted, its area of surface growing less and less as it rose, until the
smallest area possible under the conditions was attained.
[Illustration: __Fig._ 3.—Thread of golden syrup rising and forming a
drop._]
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