Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
conception, derived from Carnot, of a reversible engine as the engine of
greatest efficiency, and to deduce in a highly original manner all the
consequences of these doctrines which go to make up the ordinary
thermodynamics even of the present time. Though Clausius was the first,
as we shall see, to deduce various important theorems, yet Thomson's
discussion of the question had a quality peculiarly its own. It was
marked by that freedom from unstated assumptions, from extraneous
considerations, from vagueness of statement and of thought, which
characterises all his applications of mathematics to physics. The
physical ideas are always set forth clearly and in such a manner that
their quantitative representation is immediate: we shall have an example
of this in the doctrine of absolute temperature. In most of the
thermodynamical discussions which take the great memoir of Clausius as
their starting point, temperature is supposed to be given by a
hypothetical something which is called a perfect gas, and it is very
difficult, if not impossible, to gather a precise notion of the
properties of such a gas and of the temperature scale thereon founded.
Thomson's scale enables a perfect gas to be defined, and the deviations
of the properties of ordinary gases from those of such a gas to be
observed and measured.
The idea, then, which Joule had communicated to Section A, when Thomson
interposed to call attention to its importance, was that work spent in
overcoming friction had its equivalent in the heat produced, that, in
fact, the amount of heat generated in such a case was proportional to
the work spent, quite irrespective of the materials used in the process,
provided no change of the internal energy of any of them took place so
as to affect the resulting quantity of heat. This forced upon physicists
the view pointed to by the doctrine of the immateriality of heat,
established by the experiments of Rumford and Davy, that heat itself was
a form of energy; and thus the principle of conservation of energy was
freed from its one defect, its apparent failure when work was done
against friction.
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