Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
The inverse process, the conversion of heat into work, required
investigation, and it is this that constitutes the science of
thermodynamics. It was the subject of the celebrated _Réflexions sur la
Puissance Motrice du Feu, et sur les Machines Propres à Développer cette
Puissance_, published in 1824 by Sadi Carnot, an uncle of the late
President of the French Republic. Only a few copies of this essay were
issued, and its text was known to very few persons twenty-four years
later, when it was reprinted by the Academy of Sciences. Its methods and
conclusions were set forth by Thomson in 1849 in a memoir which he
entitled, "An Account of Carnot's Theory of the Motive Power of Heat."
Numerical results deduced from Regnault's experiments on steam were
included; and the memoir as a whole led naturally in Thomson's hands to
a corrected theory of heat engines, which he published in 1852. Carnot's
view of the working of a heat engine was founded on the analogy of the
performance of work by a stream of water descending from a higher level
to a lower. The same quantity of water flows away in a given time from a
water wheel in the tail-race as is received in that time by the wheel
from the supply stream. Now a heat engine receives heat from a supplying
body, or source, at one temperature and parts with heat to another body
(for example, the condenser of a steam engine) at a lower temperature.
This body is usually called the refrigerator. According to Carnot these
temperatures corresponded to the two levels in the case of the water
wheel; the heat was what flowed through the engine. Thus in his theory
as much heat was given up by a heat engine to the body at the lower
temperature as was received by it from the source. The heat was simply
transferred from the body at the higher temperature to the body at the
lower; and this transference was supposed to be the source of the
work.[17]
The first law of thermodynamics based on Joule's proportionality of heat
produced to work expended, and the converse assumed and verified _a
posteriori_, showed that this view is erroneous, and that the heat
delivered to the refrigerator must be less in amount than that received
from the source, by exactly the amount which is converted into work,
together with the heat which, in an imperfect engine, is lost by
conduction, etc., from the cylinder or other working chamber. This
change was made by Thomson in his second paper: but he found the ideas
of Carnot of direct and fruitful application in the new theory. These
were the cycle of operations and the ideal reversible engine.
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