Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
In the Carnot cycle the working substance--which might be a gas or a
vapour, or a liquid, or a vapour and its liquid in contact: it did not
matter what for the result--was supposed to be put through a succession
of changes in which the final state coincided with the initial. Thus the
substance having been brought back to the same physical condition as it
had when the cycle began, has the same internal energy as it had at the
beginning, and in the reckoning of the work done by or against external
forces, nothing requires to be set to the account of the working
substance. This is the first great advantage of the method of reasoning
which Carnot introduced.
The ideal engine was a very simple affair: but the notion of
reversibility is difficult to express in a form sufficiently definite
and precise. Carnot does not attempt this; he merely contents himself
with describing certain cycles of operations which obviously can be
carried through in the reverse order. Nor does Thomson go further in his
"Account of Carnot's Theory," though he states the criterion of a
perfect engine in the words, "A perfect thermodynamic engine is such
that, whatever amount of mechanical effect it can derive from a certain
thermal agency, if an equal amount be spent in working it backwards, an
equal reverse thermal effect will be produced." This proposition was
proved by Carnot: and the following formal statement in the essay is
made: "La puissance motrice de la chaleur est independante des agents
mis en œuvre pour la réaliser: sa quantité est fixée uniquement par
les temperatures des corps entre lesquels se fait, en dernier résultat,
le transport du calorique." The result involved in each, that the work
done in a cycle by an ideal engine depends on the temperatures between
which it works and not at all on the working substance, is, as we shall
see, of the greatest importance. The proof of the proposition, by
supposing a more efficient engine than the ideal one to exist, and to be
coupled with the latter, so that the more efficient would perform the
cycle forwards and the ideal engine the same cycle backwards, is well
known. In Carnot's view the former would do more work by letting down a
given quantity of heat from the higher to the lower temperature than was
spent on the latter in transferring the same quantity of heat from the
lower to the higher temperature, so that no heat would be taken from or
given to source or refrigerator, while there would be a gain of work on
the whole. This would be equivalent to admitting that useful work could
be continually performed without any resulting thermal or other change
in the agents performing the work. Even at that time this could not be
admitted as possible, and hence the supposition that a more efficient
engine than the reversible one could exist was untenable.
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