Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Carnot showed that the work done by an ideal engine, in transferring
heat from one temperature to another, was to be found by means of a
certain function of the temperature, hence called "Carnot's function."
The corresponding function in the true dynamical theory is always called
Carnot's. A certain assignment of value to it gave, as we shall see,
Thomson's famous absolute thermodynamic scale of temperature.
In the light of the facts and theories which now exist, and are almost
the commonplaces of physical text books, it is very interesting to
review the ideas and difficulties which occurred to the founders of the
science of heat sixty years ago. For example, Thomson asks, in his
"Account of Carnot's Theory," what becomes of the mechanical effect
which might be produced by heat which is transferred from one body to
another by conduction. The heat leaves one body and enters another and
no mechanical effect results: if it passed from one to the other through
a heat engine, mechanical effect would be produced: what is produced in
place of the mechanical effect which is lost? This he calls a very
"perplexing question," and hopes that it will, before long, be cleared
up. He states, further, that the difficulty would be entirely avoided by
abandoning Carnot's principle that mechanical effect is obtained by "the
transference of heat from one body to another at a lower temperate."
Joule urges precisely this solution of the difficulty in his paper, "On
the Changes of Temperature produced by the Rarefaction and Condensation
of Air" (_Phil. Mag._, May 1845). Thomson notes this, but adds, "If we
do so, however, we meet with innumerable other difficulties--insuperable
without further experimental investigation, and an entire reconstruction
of the theory of heat from its foundation. It is in reality to
experiment that we must look, either for a verification of Carnot's
axiom, and an explanation of the difficulty we have been considering, or
for an entirely new basis of the Theory of Heat."
The experiments here asked for had already, as was soon after perceived
by Thomson, been made by Joule, not merely in his determinations of the
dynamical equivalent of heat, but in his exceedingly important
investigation of the energy changes in the circuit of a voltaic cell, or
of a magneto-electric machine. Moreover, the answer to this "very
perplexing question" was afterwards to be given by Thomson himself in
his paper, "On a Universal Tendency in Nature to the Dissipation of
Mechanical Energy," published in the Edinburgh Proceedings in 1852.
Public-domain text, read in full here on John Shaqi.
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