Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
It is worthy of notice that the indicator-diagram method of graphically
representing the changes in a cycle of operations is adopted in
Thomson's "Account," but does not occur in Carnot's essay. The cycles
consist of two isothermal changes and two adiabatic changes; that is,
two changes at the temperatures of the source and refrigerator
respectively, and two changes--from the higher to the lower temperature,
and from the lower to the higher. These changes are made subject to the
condition in each case that the substance neither gains nor loses energy
in the form of heat, but is cooled in the one case by expansion and
heated in the other by compression. The indicator diagram was due not to
Thomson but to Clapeyron (see p. 99 above), who used it to illustrate an
account of Carnot's theory.
There appeared in the issue of the Edinburgh _Philosophical
Transactions_ for January 2, 1849, along with the "Account of Carnot's
Theory," a paper by James Thomson, entitled, "Theoretical Considerations
on the Effect of Pressure in Lowering the Freezing Point of Water." The
author predicted that, unless the principle of conservation of energy
was at fault, the effect of increase of pressure on water in the act of
freezing would be to lower the freezing point; and he calculated from
Carnot's theory the amount of lowering which would be produced by a
given increment of pressure. The prediction thus made was tested by
experiments carried out in the Physical Laboratory by Thomson, and the
results obtained completely confirmed the conclusions arrived at by
theory. This prediction and its verification have been justly regarded
as of great importance in the history of the dynamical theory of heat;
and they afford an excellent example of the predictive character of a
true scientific theory. The theory of the matter will be referred to in
the next chapter.
CHAPTER VIII
THERMODYNAMICS AND ABSOLUTE THERMOMETRY
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