Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
The first statement of the true dynamical theory of heat, based on the
fundamental idea that the work done in a Carnot cycle is to be accounted
for by an excess of the heat received from the source over the heat
delivered to the refrigerator, was given by Clausius in a paper which
appeared in _Poggendorff's Annalen_ in March and April 1850, and in the
_Philosophical Magazine_ for July 1850, under a title which is a German
translation of that of Carnot's essay. In that paper the First Law of
Thermodynamics is explicitly stated as follows: "In all cases in which
work is produced by the agency of heat, a quantity of heat proportional
to the amount of work produced is expended, and, inversely, by the
expenditure of that amount of work exactly the same amount of heat is
generated." Modern thermodynamics is based on this principle and on the
so-called Second Law of Thermodynamics; which is, however, variously
stated by different authors. According to Clausius, who used in his
paper an argument like that of Carnot based on the transference of heat
from the source to the refrigerator, the foundation of the second law
was the fact that heat tends to pass from hotter to colder bodies. In
1854 (_Pogg. Ann._, Dec. 1854) he stated his fundamental principle
explicitly in the form: "Heat can never pass from a colder to a hotter
body, unless some other change, connected therewith, take place at the
same time," and gives in a note the shorter statement, which he regards
as equivalent: "Heat cannot of itself pass from a colder to a hotter
body."
We shall not here discuss the manner in which Clausius applied this
principle: but he arrived at and described in his paper many important
results, of which he must therefore be regarded as the primary
discoverer. His theory as originally set forth was lacking in clearness
and simplicity, and was much improved by additions made to it on its
republication, in 1864, with other memoirs on the Theory of Heat.
In the _Transactions R.S.E._, for March 1851, Thomson published his
great paper, "On the Dynamical Theory of Heat." The object of the paper
was stated to be threefold: (1) To show what modifications of Carnot's
conclusions are required, when the dynamical theory is adopted: (2) To
indicate the significance in this theory of the numerical results
deduced from Regnault's observations on steam: (3) To point out certain
remarkable relations connecting the physical properties of all
substances established by reasoning analogous to that of Carnot, but
founded on the dynamical theory.
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