Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
In the Carnot cycle, the first operation is an isothermal expansion (AB
in Fig. 12), in which the substance increases in volume by dv, and takes
in from the source heat of amount Mdv. The second operation is an
adiabatic expansion, BC, in which the volume is further increased and
the temperature sinks by dt to the temperature of the refrigerator. The
third operation is an isothermal compression, CD, until the volume and
pressure are such that an adiabatic compression DA will just bring the
substance back to the original state. If ∂p⧸∂t be the rate of
increase of pressure with temperature when the volume is constant, the
step of pressure from one isothermal to the other is ∂p⧸∂t.dt; and
thus the area of the closed cycle in the diagram which measures the
external work done in the succession of changes is ∂p⧸∂t.dtdv. Now,
by the second law, the work done must be a certain fraction of the
work-equivalent of the heat, Mdv, taken in from the source. This
fraction is independent of the nature of the working substance, but
varies with the temperature, and is therefore a function of the
temperature. Its ratio to the difference of temperature dt between
source and refrigerator was called "Carnot's function," and the
determination of this function by experiment was at first perhaps the
most important problem of thermodynamics. Denoting it by μ, we have
the equation
∂p⧸∂t = μM ... (A)
which may be taken as expressing in mathematical language the second law
of thermodynamics. M is here so chosen that Mdv is the heat expressed in
units of work, so that μ does not involve Joule's equivalent of heat.
This equation was given by Carnot: it is here obtained by the dynamical
theory which regards the work done as accounted for by disappearance,
not transference merely, of heat.
The work done in the cycle becomes now μMdtdv, or if H denote Mdv, it
is μHdt. The fraction of the heat utilised is thus μdt. This is
called the efficiency of the engine for the cycle.
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