Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Thomson's demonstration that a reversible engine is the most efficient
is well known, and need not here be repeated in detail. The reversible
engine may be worked backwards, and the working substance will take in
heat where in the direct action it gave it out, and _vice versa_: the
substance will do work against external forces where in the direct
action it had work done upon it, and _vice versa_: in short, all the
physical and mechanical changes will be of the same amount, but merely
reversed, at every stage of the backward process. Thus if an engine A be
more efficient than a reversible one B, it will convert a larger
percentage of an amount of heat H taken in at the source into work than
would the reversible one working between the same temperatures. Thus if
h be the heat given to the refrigerator by A, and h' that given by B
when both work directly and take in H; h must be less than h'. Then
couple the engines together so that B works backwards while A works
directly. A will take in H and deliver h, and do work equivalent to
H - h. B will take h' from the refrigerator and deliver H to the source,
and have work equivalent to H - h' spent upon it. There will be no heat
on the whole given to or taken from the source; but heat h' - h will be
taken from the refrigerator, and work equivalent to this will be done.
Thus _by a cyclical process_, which leaves the working substance as it
was, work is done at the expense of heat taken from the refrigerator,
which Thomson's postulate affirms to be impossible. Therefore the
assumption that an engine more efficient than the reversible engine
exists must be abandoned; and we have the conclusion that all reversible
engines are equally efficient.
Thomson acknowledged in his paper the priority of Clausius in his proof
of this proposition, but stated that this demonstration had occurred to
him before he was aware that Clausius had dealt with the matter. He now
cited, as examples of the First Law of Thermodynamics, the results of
Joule's experiments regarding the heat produced in the circuits of
magneto-electric machines, and the fact that when an electric current
produced by a thermal agency or by a battery drives a motor, the heat
evolved in the circuit by the passage of the current is lessened by the
equivalent of the work done on the motor.
[Illustration: FIG. 12.]
Public-domain text, read in full here on John Shaqi.
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