Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
changes specified, be the area of the cycle or (v₂ - v₁)∂p⧸∂T.dT.
But by equation (B) L⧸T(v₂ - v₁) = ∂p⧸∂T, and the area of the cycle is
(L⧸T)dT. Equating the two expressions thus found for the area we get
equation (C).
This relation was arrived at by Clausius in his paper referred to above,
and the priority of publication is his: it is here given in the form
which it takes when Thomson's scale of absolute temperature is used.
Regnault's experimental results for the heat required to raise unit mass
of water from the temperature of melting ice to any higher temperature
and evaporate it at that temperature enable the values of L⧸T and
∂L⧸∂T to be calculated, and therefore that of h to be found. It
appears that h is negative for all the temperatures to which Regnault's
experimental results can be held to apply. This, as was pointed out by
Thomson, means that if a mass of saturated vapour is made to expand so
as at the same time to fall in temperature, it must have heat given to
it, otherwise it will be partly condensed into liquid; and, on the other
hand, if the vapour be compressed and made to rise in temperature while
at the same time it is kept saturated, heat must be taken from it,
otherwise the vapour will become superheated and so cease to be
saturated.
It is convenient to notice here the article on Heat which Thomson wrote
for the ninth edition of the _Encyclopædia Britannica_. In that article
he gave a valuable discussion of ordinary thermometry, of thermometry by
means of the pressures of saturated vapour of different
substances--steam-pressure thermometers, he called them--of absolute
thermodynamic thermometry, all enriched with new experimental and
theoretical investigations, and appended to the whole a valuable
synopsis, with additions of his own, of the Fourier mathematics of heat
conduction.
First dealing with temperature as measured by the expansion of a liquid
in a less expansible vessel, he showed how it is in reality numerically
reckoned. This amounted to a discussion of the scale of an ordinary
mercury-in-glass thermometer, a subject concerning which erroneous
statements are not infrequently made in text-books. A sketch of
Thomson's treatment of it is given here.
Public-domain text, read in full here on John Shaqi.
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