Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Considering this thermometer as a vessel consisting of a glass bulb and
a long glass stem of fine and uniform bore, hermetically sealed and
containing only mercury and mercury vapour, he explained the numerical
relation between the temperature as shown by the instrument and the
volumes of the mercury and vessel. The scale is really defined by the
method of graduation adopted. Two points of reference are marked on the
stem at which the top of the mercury stands when the vessel is immersed
(1) in melting ice, (2) in saturated steam under standard atmospheric
pressure. The stem is divided into parts of equal volume of bore between
these two points and beyond each of them. For a centigrade thermometer
the bore-space between the two points is divided into 100 equal parts,
and the lower point of reference is marked 0 and the upper 100, and the
other dividing marks are numbered in accordance with this along the
stem. Each of these parts of the bore may be called a degree-space.
Now let the instrument contain in its bulb and stem, up to the mark 0, N
degree-spaces, and let v be the volume of a degree-space at that
temperature. The volume up to the mark 0 will be Nv, at that
temperature; and if the substance of the vessel be quite uniform in
quality and free from stress, N will be the same for all temperatures.
If v₀ be the volume of a degree-space at the temperature of melting ice
the volume of the mercury at that temperature will be Nv₀. If G be the
expansion of the glass when the volume of a degree-space is increased
from v₀ to v by the rise of temperature, then v = v₀(1 + G). The
volume of the mercury has been increased therefore to (N + n)v₀(1 + G)
by the same rise of temperature, if the top of the column is thereby
made to rise from the mark 0 so as to occupy n degree-spaces more than
before. But if E be the expansion of the mercury between the temperature
of melting ice and that which has now been attained, the volume of the
mercury is also Nv₀(1 + E). Hence N(1 + E) = (N + n)(1 + G). This gives
n = N(E - G)⧸(1 + G).
If we take, as is usual, n as measuring the temperature, and substitute
for it the symbol t, we have, since N = 100(1 + G₁₀₀)⧸(E₁₀₀ - G₁₀₀),
t = 100 {(1 + G₁₀₀)⧸(1 + G)} {(E - G)⧸(E₁₀₀ - G₁₀₀)} ... (D)
Public-domain text, read in full here on John Shaqi.
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