Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
In connection with the theory of heat must be mentioned Thomson's great
generalisation, the theory of the dissipation of energy.[19] Most people
have some notion of the meaning of the physical doctrine of
conservation of energy, though in popular discourses it is usually
misstated. What is meant is that in a finite material system, which is
isolated in the sense that it is not acted on by force from without, the
total amount of energy--that is, energy of motion and energy of relative
position (including energy of chemical affinity) of the parts--remains
constant. The usual misstatement is that the energy of the universe is
constant. This may be true if the universe is finite; if the universe is
infinite in extent the statement has no meaning. In any case, we know
nothing about the universe as a whole, and therefore make no statements
regarding it.
But while there is thus conservation or constancy of amount of energy in
an isolated and finite material system, this energy may to residents on
the system become unavailable. For useful work within such a system is
done by conversion of energy from one form to another and the total
amount remains unchanged. But if this conversion is prevented all
processes which involve such conversion must cease, and among these are
vital processes.
The unavailable form which the energy of the system with which we are
directly and at present concerned, whatever may become of us ultimately,
is taking, according to Thomson's theory, is universally diffused heat.
How this comes about may be seen as follows. Even a perfect engine, if
the refrigerator be at the lowest available temperature, rejects a
quantity of heat which cannot be utilised for the performance of the
work. This heat is diffused by conduction and radiation to surrounding
bodies, and so to bodies more remote, and the general temperature of
the system is raised. Moreover, as heat engines are imperfect there is
heat rejected to the surroundings by conduction, and produced by work
done against friction, so that the heat thrown on the unavailable or
waste heap is still further increased.
Conduction of heat is the great agency by which energy is more and more
dispersed in this unavailable form throughout the totality of material
bodies. As has been seen, available motivity is continually wasted
through its agency; and in the flow of heat in the earth and in the sun
and other unequally heated bodies of our system the waste of energy is
prodigious. Aided by convection currents in the air and in the ocean it
continually equalises temperatures, but does so at an immense cost of
useful energy.
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