Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
The cooling effect of passing a gas such as air or oxygen through a
narrow orifice has been used to liquefy the gas. The stream of gas is
pumped along a pipe towards the opening, and that which has passed the
orifice and been slightly cooled is led on its way back to the pump
along the outside of the pipe by which more gas is approaching the
orifice, and so cools slightly the advancing current. The gas which
emerges later is thus cooler than that which emerged before, and the
process goes on until the issuing gas is liquefied and falls down into
the lower part of the pipe surrounding the orifice, whence it can be
drawn off into vessels constructed to receive and preserve it.
It is possible thus to liquefy hydrogen, which shows that at the low
temperature at which the process is usually started (an initial cooling
is applied) the passage through the orifice has a cooling effect as in
the other cases.
Another idea, that of _thermodynamic motivity_, on which Thomson
suggested might be founded a fruitful presentation of the subject of
thermodynamics, may be mentioned here. It was set forth in a letter
written to Professor Tait in May 1879. If a system of bodies be given,
all at different temperatures, it is possible to reduce them to a common
temperature, and by doing so to extract a certain amount of mechanical
energy from them. The temperatures must for this purpose be equalised
by perfect thermodynamic engines working between the final temperature
T₀, say, and the temperatures of the different parts of the system.
This process is one of the levelling up and the levelling down of
temperature; and the temperature T₀ is such that exactly the heat given
out at T₀ by certain engines, receiving heat from bodies of higher
temperature than T₀, is supplied to the engines which work between T₀
and bodies at lower temperatures. The whole useful work obtained in this
way was called by Thomson the motivity of the system. Of course
equalisation of temperature may be obtained by conduction, and in this
case the energy which might be utilised is lost. With two equal and
similar bodies at absolute temperatures T, T' the temperature to which
they are reduced when their motivity is extracted is √(TT'). If the
temperatures are equalised by conduction the resulting temperature is
higher, being ½(T + T'). Thus, if only the two bodies are available
for engines to work between, the motivity is the measure of the energy
lost when conduction brings about equalisation of temperature.
A very suggestive paper on the subject was published by Lord Kelvin in
the _Trans. R.S.E._, vol. 28, 1877-8.
DISSIPATION OF ENERGY
Public-domain text, read in full here on John Shaqi.
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