Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Thomson had, however, previous to the publication of this paper, applied
thermodynamic theory to thermoelectric phenomena. A long series of
papers containing experimental investigations, and entitled,
"Electrodynamic Qualities of Metals," are placed in the second volume of
his _Mathematical and Physical Papers_. This series begins with the
Bakerian Lecture (published in the _Transactions of the Royal Society_
for 1856) which includes an account of the remarkable experimental work
accomplished during the preceding four or five years by the volunteer
laboratory corps in the newly-established physical laboratory in the old
College. The subjects dealt with are the Electric Convection of Heat,
Thermoelectric Inversions, the Effects of Mechanical Strain and of
Magnetisation on the Thermoelectric Qualities of Metals, and the Effects
of Tension and Magnetisation on the Electric Conductivity of Metals. It
is only possible to give here a very short indication of the
thermodynamic treatment, and of the nature of Thomson's remarkable
discovery of the electric convection of heat.
It was found by Seebeck in 1822 that when a circuit is formed of two
different metals (without any cell or battery) a current flows round the
circuit if the two junctions are not at the same temperature. For
example, if the two metals be rods of antimony and bismuth, joined at
their extremities so as to form a complete circuit, and one junction be
warmed while the other is kept at the ordinary temperature, a current
flows across the hot junction in the direction from bismuth to antimony.
Similarly, if a circuit be made of a copper wire and an iron wire, a
current passes across the warmer junction from copper to iron. The
current strength--other things being the same--depends on the metals
used; for example, bismuth and antimony are more effective than other
metals.
It was found by Peltier that when a current, say from a battery, is sent
round such a circuit, that junction is cooled and that junction is
heated by the passage of the current, which, being respectively heated
and cooled, would without the cell have caused a current to flow in the
same direction. Thus the current produced by the difference of
temperature of the junctions causes an absorption of heat from the
warmer junction, and an evolution of heat at the colder junction.
This naturally suggested to Thomson the consideration of a circuit of
two metals, with the junctions at different temperatures, as a heat
engine, of which the hot junction was the source and the cold junction
the refrigerator, while the heat generated in the circuit by the current
and other work performed, if there was any, was the equivalent of the
difference between the heat absorbed and the heat evolved. Of course in
such an arrangement there is always irreversible loss of heat by
conduction; but when such losses are properly allowed for the circuit is
capable of being correctly regarded as a reversible engine.
Public-domain text, read in full here on John Shaqi.
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