Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Shortly after Seebeck's discovery it was found by Cumming that when the
hot junction was increased in temperature the electromotive force
increased more and more slowly, at a certain temperature of the hot
junction took its maximum value, and then as the temperature of the hot
junction was further increased began to diminish, and ultimately, at a
sufficiently high temperature, in most instances changed sign. The
temperature of maximum electromotive force was found to be independent
of the temperature of the colder junction. It is called the temperature
of the neutral point, from the fact that if the two junctions of a
thermoelectric circuit be kept at a constant small difference of
temperature, and be both raised in temperature until one is at a higher
temperature than the neutral point, and the other is at a lower, the
electromotive force will fall off, until finally, when this point is
reached, it has become zero.
Thus it was found that for every pair of metals there was at least one
such temperature of the hot junction, and it was assumed, with
consequences in agreement with experimental results, that when the
temperature was the neutral temperature there was neither absorption nor
evolution of heat at the junction. But then the source provided by the
thermodynamic view just stated had ceased to exist. The current still
flowed, there was evolution of heat at the cold junction, and likewise
Joulean evolution of heat in the wires of the circuit in consequence of
their resistance. Hence it was clear that energy must be obtained
elsewhere than at the junctions. Thomson solved the problem by showing
that (besides the Joulean evolution of heat) there is absorption (or
evolution) of heat when a current flows in a conductor along which there
is a gradient of temperature. For example, when an electric current
flows along an unequally heated copper wire, heat is evolved where the
current flows from the hot parts to the cold, and heat is absorbed where
the flow is from cold to hot. When the hot junction is at the
temperature of zero absorption or evolution of heat--the so-called
neutral temperature--the heat absorbed in the flow of the circuit along
the unequally heated conductors is greater than that evolved on the
whole, by an amount which is the equivalent of the energy electrically
expended in the circuit in the same time.
Public-domain text, read in full here on John Shaqi.
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