Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
(_e_) _Lime water._ This reagent may be said to decompose corrosive
sublimate more perfectly than any alkaline body; occasioning a
precipitate of a deep yellow colour, which will be found to be a
peroxide of mercury; unless indeed the quantity of lime water be very
small, when it will be a sub-muriate of the peroxide.
(_f_) _Nitrate of Tin._ According to _Dr. Bostock_[287] this test is
capable of detecting the three-millionth part of a grain in solution. A
single drop will produce an immediate and copious dark-brown
precipitation.
All the above precipitates, if rubbed on a bright plate of copper, will
render its surface silvery white, in consequence of the amalgamation
which takes place.
_Brugnatelli_ has lately proposed a method of distinguishing _corrosive
sublimate_ from _arsenic_, which we have repeated to our satisfaction;
but the experiment requires some nicety of manipulation to secure its
success. Take a quantity of fresh wheat starch, mix with water, and add
a sufficient quantity of _iodine_ to give the liquid a blue colour; if
either of the above poisons be now introduced into it, the colour will
be destroyed, and assume a reddish tint; but if the change has been
effected by the latter substance, a few drops of sulphuric acid will
restore the blue colour; whereas if it has been produced by the former,
it is not recoverable by such means.[288]
3. _It is dissolved in various coloured liquids._ Under this subdivision
we have to consider the corrosive sublimate as existing in a state of
solution, in liquids, whose colour will be liable to obscure the
characteristic indications which the several reagents would otherwise
occasion. It has been proposed to obviate such impediments by the
previous addition of chlorine, which will discharge the colour in
question. _Orfila_ recommends such a process, where the salt has been
dissolved in wine. The same objections which we urged against this mode
of proceeding, under the consideration of arsenic, appear to us to apply
to corrosive sublimate.
It will be preferable on these occasions to precipitate the salt by an
appropriate reagent, and then to assay the precipitate for metallic
mercury; or to evaporate the solution, and to submit the matter so
obtained to the process of sublimation, when the sublimate may be
dissolved in distilled water, and examined by the tests above described.
This circuitous process may, however, in many cases be rendered
unnecessary, by dropping the solution on the surface of white paper, and
in such a situation proceeding to its examination by tests; when the
colour of the precipitate will rarely be exposed to any optical fallacy.
The Galvanic process of metallic reduction will also furnish a
satisfactory solution of the problem.
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