Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
(_b_) _By precipitating metallic mercury from its solution, by the
contact of a single metal._ It should be generally known that, by virtue
of superior affinity, certain metals will decompose the solution of
corrosive sublimate, with different phenomena; in those cases where the
precipitating metal is capable of forming a direct union with mercury,
we shall find the precipitates to consist of an amalgam of the metal
employed; where no such combination takes place, the mercury may be
frequently seen standing on the surface as a metallic dew. This is
particularly striking when iron or steel has been employed. In the
evidence given on the trial of _Mary Bateman_[283], better known by the
name of the “Yorkshire Witch,” _Mr. Thomas Chorley_, surgeon at Leeds,
stated that he had received from his assistant, _Mr. Hammerton_, a jar
which he had carefully preserved in his possession, and of the contents
of which he gave the following account. “Upon tasting a portion, it was
very acrid, styptic, and permanent upon the tongue; I then took a small
quantity of it upon a clean knife, and rubbed it with my finger; a
change of colour immediately appeared; _further rubbing produced
numerous globules of quicksilver_, and the knife was, at the same time,
blackened by it; this change of colour led me to suspect that it must be
a mercurial composition, and having made a solution of it, and subjected
it to a series of tests and experiments, it is my opinion, that the
mixture in the pot did contain _honey_, and _corrosive sublimate of
mercury_. In order, however, more fully to satisfy myself upon this
point, a mixture was made of these ingredients, when it was found to
yield the same results.” In the above experiment, the steel knife
decomposed the sublimate, forming a _chloride of iron_, while the
mercury, thus disengaged in its metallic form, being unable to
amalgamate with the iron, appeared in globules[284] upon its surface. At
the same time the knife _became blackened_ owing to the precipitation of
carbonaceous matter from the steel.
(_c_) _Carbonate of Potass._ A saturated solution of this salt, added to
that of corrosive sublimate, will produce a _deep brick coloured_
sediment, which is stated to consist of per-carbonate of mercury[285];
while a muriate of potass will be found to remain in solution. The
_sub-carbonate of potass_ will occasion a somewhat different
precipitate, of a _clear brick_ colour, and consisting of a mixture of
the carbonate, and oxide of the metal.[286]
(_d_) _Ammonia._ A solution of the volatile alkali produces a _white
precipitate_, which is an insoluble triple salt, composed of muriatic
acid, ammonia, and oxide of mercury; being heated it grows yellow; it
passes afterwards to red, and according to _Orfila_ gives out ammoniacal
gas, nitrogen, calomel, and metallic mercury. In this operation the
oxide of mercury is supposed to be deoxidized by the hydrogen which
results from a portion of the decomposed ammonia.
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