To examine a piece of cloth stained with this poison it is only
necessary to boil it in distilled water and then apply to the liquid the
barium test as before.
NITRIC ACID (_Aqua fortis_, _Red Spirit of Nitre_).—This substance has
been employed as a poison for upwards of four centuries. Like the oil of
vitriol it is found in commerce in a concentrated and in a diluted
state. Cases of poisoning by it are rare. It produces a yellow stain on
the skin. Two drachms is the smallest quantity which has destroyed life;
but less than this would probably prove fatal, if it produced much
corrosion about the wind-pipe. Death has occurred from it, in one hour
and three quarters; the average would be within twenty-four hours.
Several cases ending fatally have followed the inhalation of the fumes
of this acid, probably by inducing very extensive inflammation of the
lung.
_Tests._—The concentrated acid may be known by its orange-colored
irritating fumes, and by its action on copper, tin, or mercury.
1. When poured on copper-filings, effervescence takes place, a red acid
vapor is given off, and a green liquid remains (solution of nitrate of
copper).
2. In a diluted state it is detected by its acid reaction; by no
precipitate being obtained by nitrate of barium or by nitrate of silver,
proving the absence of sulphuric and hydrochloric acids; further, by
neutralizing the liquid with potass, evaporating it, and then procuring
crystals of nitrate of potassium, in the form of lengthened fluted
prisms, which are permanent in the air. These crystals may be powdered
and moistened with strong sulphuric acid, when a colorless acid vapor
(nitric acid) will be evolved. Or the powdered crystals may be mixed
with an equal bulk of fine copper filings, moistened with water, and
treated with a few drops of sulphuric acid; when ruddy acid fumes will
be given off.
3. Other tests for nitric acid are, (_a_,) its action on morphia, which
it turns red: (_b_,) its action on green iron sulphate, which it
blackens; (_c_,) a trace of it along with sulphuric acid gives with
narcotine a blood red color; and finally, (_d_,) along with hydrochloric
acid it dissolves gold.
HYDROCHLORIC ACID (_Muriatic Acid_, _Spirit of Salt_).—Not more than
half a dozen cases of poisoning by this acid have occurred in the last
fifteen or twenty years in this country. In May, 1859, a woman
sixty-three years old was admitted into King’s College Hospital within
three-quarters of an hour of swallowing half an ounce of the strong
acid. She had burning pain in the throat and stomach, vomiting of brown
shreddy matters, and great prostration. Death occurred in eighteen
hours, from the corrosive action of the poison. This is the smallest
dose which has been known to prove fatal.
_Tests._—The concentrated hydrochloric acid of commerce is of a
yellowish color, it fumes in the air when strong, and produces dense
white fumes with the vapor of ammonia.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account