Lime water and all soluble lime salts throw down precipitates with
oxalic acid; but as these are liable to be mistaken for a precipitate
with sulphuric acid, it is better to use sulphate of calcium which is
slightly soluble, as the test agent. A good deal of the test solution
must be used, and the precipitate takes time to settle.
3. _Sulphate of copper_ gives a faint bluish precipitate with oxalic
acid (oxalate of copper), which is not redissolved by a few drops of
hydrochloric acid.
These tests will not act if the solution contain nitric acid in excess,
in which case the liquid must be evaporated to crystallization, and the
crystals washed and redissolved in water.
These tests for oxalic acid should never be applied without previously
separating it from all organic matter. This is best done by first of all
acidulating the suspected fluid with acetic acid, and then adding
acetate of lead, which combines with the oxalic acid to form a white
insoluble salt, which may ordinarily be removed by filtration or
subsidence. This filtrate, after being well washed, is to be diffused in
water, and into this a current of sulphuretted hydrogen gas is to be
passed for some considerable time. This will throw down the lead as
sulphide, leaving the oxalic acid in the fluid; any organic matter will
also be carried down. Filtration will separate the solids from the
liquid containing the acid, which may now be evaporated until crystals
are formed, which may be tested in the usual way.
ACETIC ACID.—Although this acid, in its concentrated state, is highly
corrosive, yet it is very seldom brought under the notice of the
toxicologist.
In the case of a young woman reported by Orfila, death quickly occurred
after several attacks of convulsions. At the subsequent post-mortem
examination, the integuments of the dependent parts of the body were
found very livid; the tongue and œsophagus were of a dirty brown
color, the latter being intersected by a fine net-work of capillary
vessels; and the interior of the stomach was interspersed with black
elevations caused by the presence of coagulated blood in the sub-mucous
areolar tissue. The mucous membrane was entire.
As regards the _treatment_, it is only necessary to administer draughts
containing magnesia or its carbonate, followed by mucilaginous or
demulcent drinks.
TARTARIC ACID, though not a corrosive, may be here placed along with the
other vegetable acids. Strange as it may seem, tartaric acid has
destroyed life in at least one instance in this country; an ounce having
been given in mistake for an aperient salt. The deceased swallowed the
whole at once, and immediately called out that he had been poisoned. He
complained of intense pain in the throat and stomach, as if he had
swallowed oil of vitriol, or was on fire. Soda and magnesia were
administered without avail; and after death, at the end of nine days’
suffering, the stomach and intestines were found much inflamed.
CHAPTER VIII.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account