_Marsh’s Test or Process._—This process is founded on the decomposition
of arsenious acid by nascent hydrogen, and the formation of arsenuretted
hydrogen gas, which possesses the following properties: It burns with a
bluish-white flame, and white smoke (arsenious acid), possessing a
slight garlic odor. If a piece of glass or porcelain be held in the
flame a blackish metallic stain will be deposited upon it, consisting of
metallic arsenic. This stain might be confounded with one produced by
antimony under similar circumstances. But the antimonuretted hydrogen
gas does not burn with the odor of the arsenuretted hydrogen; while the
antimonial stain is sooty, and has not a metallic lustre. The arsenical
stain is further readily dissolved by a solution of chloride of lime
(bleaching powder), whilst the antimonial stain is not affected. To the
stain may be added a few drops of strong nitric acid; it will dissolve
the arsenic; if this be allowed to evaporate, and the acid be
neutralized, a few drops of nitrate of silver solution will give a
brick-red precipitate of arseniate of silver.
Marsh’s test is thus accomplished: a flask furnished with a cork through
which pass a funnel and a long bent tube drawn to a point, is prepared
so that the funnel reaches almost to its bottom. Several pieces of pure
zinc are introduced, and then some sulphuric acid is poured through the
funnel. In this way hydrogen gas is produced and escapes by the bent
tube. When all the air has been expelled the gas should be ignited as it
escapes, and a piece of cool porcelain held over the flame. If there be
no deposit it is plain that neither the zinc nor the sulphuric acid,
contains arsenic. A portion of the suspected fluid is next introduced
into the flask by the funnel, and the issuing gas again tested. Should a
stain giving the characters alluded to above be produced, the fluid
contains arsenic in some form or other.
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