2. The solution may further be proved to contain antimony by passing
through it sulphuretted hydrogen or adding to it sulphide of ammonium,
either of which throws down an orange-red precipitate of sulphide of
antimony. This precipitate is soluble in strong hydrochloric acid, which
being diluted, throws down a white precipitate.
3. The three dilute mineral acids (nitric is best) throw down a white
precipitate with tartar emetic, which is soluble in excess of the acid
used or in tartaric acid.
The metal may be separated from organic substances by Marsh’s or
Reinsch’s process.
CHLORIDE OF ANTIMONY (_Terchloride_ or _Butter of Antimony_) is a
powerfully corrosive liquid. It produces violent inflammation and
corrosion of the whole intestinal canal; occasionally also drowsiness,
as from the use of a narcotic.
Dr. Taylor has collected the histories of four cases of poisoning by
butter of antimony, three of which recovered. The fourth, in which a
gentleman took from two to three ounces, proved fatal in ten hours and a
half, after producing great prostration, nausea, violent griping pain,
and tenesmus, followed by a tendency to sleep. On inspection, the whole
of the inside of the alimentary canal was blackened, as if it had been
charred; there was but little mucous membrane remaining, and the parts
were much softened.
_Treatment._—Magnesia must be administered in milk, together with the
remedies recommended in poisoning by tartar emetic.
CHAPTER XVII.
MERCURY AND ITS COMPOUNDS.
Of the preparations of mercury, corrosive sublimate is the most
important to the toxicologist; for although they all possess in a
greater or less degree poisonous properties, yet the instances in which
the other compounds have been used to destroy life are extremely rare.
The treatment in all cases must be the same. It is worthy of remark that
mercury, whilst in the metallic state, is destitute of injurious
properties, but if oxidized or otherwise rendered fit for absorption, it
may give rise to dangerous symptoms. Thus, workers in mercurial mines
suffer much, as did those who were employed in silvering looking-glasses
by the old process. Large doses (from half a pound to two pounds) have
been given in obstinate cases of constipation, intussusception, &c.,
without any remarkable effect.
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