Meta toluene sulphonic acid and related compoundsAllen, C. F. H. (Charles Francis Hitchcock)
Science
Meta toluene sulphonic acid and related compounds
Allen, C. F. H. (Charles Francis Hitchcock)
Organic compounds -- Synthesis; Sulfonic acids
This is as far as the investigation has been carried at the present
time, April twenty-fifth, but its study is being continued.
CONCLUSION
The results of this investigation may be briefly summarized as follows:
(1) Ortho toluidine may be easily converted into its sulphonic acid
in which the sulphonic acid group is in the position meta to the
methyl group.
(2) Para toluidine is converted into a mixture of two isomeric
sulphonic acids of which the one with the sulphonic acid group in
the position meta to the methyl group is obtained in a ten per cent
yield.
(3) Ortho toluidine sulphonic acid may be easily diazotized using
sodium nitrite and concentrated hydrochloric acid.
(4) The diazo compound is very stable.
(5) The diazo compound is easily decomposed with n-butyl alcohol,
the hydrogen reaction taking place.
BIBLIOGRAPHY
In addition to the references made in the thesis itself the following
authorities have been consulted for the theoretical discussion:
Beilstein, F. C., “Handbuch der organischen Chemie” 1886-1890. Voss,
Hamburg.
Victor von Richter, “Organic Chemistry” Trans. 1899-1900. P.
Blakiston’s, Philadelphia, Pa. B.P.L. 3974.160
Meyer and Jacobson, “Lehrbuch der organischen Chemie” 1893. Veit & Co.,
Leipzig. B.P.L. 3973.143
[Transcriber’s Note:
Table of contents added by transcriber.
Obvious printer errors corrected silently.
Inconsistent spelling and hyphenation are as in the original.]
End of the Project Gutenberg EBook of Meta Toluene Sulphonic Acid and
Related Compounds, by Charles Francis Hitchcock Allen
Public-domain text, read in full here on John Shaqi.
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